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Consider a perfect gas contained in a cylinder and separated by a frictionless adiabatic piston into two sections A and B. All changes in B are isothermal. There is 2 mol of the gas in each section. Initially temperatures in both sections are 300K, and the volume of both sections are 2dm^3. Energy is supplied as heat to section A and the piston moves to the right reversibly until the final volume of section B is 1dm^3. Calculate (a) the heat q(A) added to section A, (b) the work w(A) done by section A, (c) change in internal energy for both sections, (d) change in entropy for both section, and for the total system and surroundings. If numerical values cannot be obtained, indicate whether the values should be positive, negative, or are indeterminate from the info given. (Assume Cv,m=20J/Kmol)
calculate the pH of a buffer solution made by adding 10.0g of anhydrous sodium acetate (NaC2H3O2) to 100 ml of 0.100M acetic acid. sume there is no change in volume on adding the salt to the acid.
One liter of a buffer solution is prepared by dissolving 0.150 mol of NaNO2 and 0.070 mol of HCl in water. What is the pH of this solution? If the solution is diluted two fold with water, what is the pH?
The activation energy for a particular reaction is 95 kJ/mol. By what factor will the rate constant increase when the temperature is increased from 50 oC to 62 oC?
What mass of NH4Cl should the student dissolve in the solution to turn it into a buffer with pH =8.77
In acidic solution an aldonic acid is converted to a gamma lactone. Draw the structure of the gamma lactone formed from galactose, and draw a mechanism for its formation.
what would you expect to observe if KHCO3 reacted with H2SO4? what test would you perform to identify the product?
When ammonia is burned in oxygen, free nitrogen gas and water are produced. What volume of ammonia will react completely with 25.0 L of oxygen? What volume of nitrogen gas is formed?
Explain what does it mean that a system is in its ground state. What is an operatr for which the wavefunction of such system is the eigenfunction?
The rate constant of a reaction is 4.7 10-3 s-1 at 24°C and the activation energy is 33.6 kJ/mol. What is the value of k at 75°C?
Calculate the number of molecules in 37.0 mL of ethanol, CH3CH2OH. The density of ethanol is 0.789 g/mL.
Describe the reaction as endothermic or exothermic, and reversible or irreversible. B) A reaction has Horxn = 5.0 kJ/mol and a forward activation energy, Ea = 55 kJ/mol. What is the activation energy for the reverse reaction?
Compute the concentrations of all species in a 0.900 M sodium sulfite solution. If it is given that the ionization constants for H2SO3 are Ka1=1.4x10^-2 and Ka2=6.3x10^-8.
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