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A 4.97 g sample of petroleum was decomposed by wet-ashing and then diluted to 500 mL in a volumetric flask. Cobalt was determined by treating 25.00 mL aliquots of this diluted solution with an organic molecule, called a ligand, that binds cobalt with a colour change (colourless to green).
The data is shown in the table below:
Reagent volume (mL)
Co2+ (3.00 ppm) Ligand (0.010 M) H2O Absorbance (600 nm)
0.00 20.00 5.00 0.398
5.00 20.00 0.00 0.510
It is known that the Co2+-ligand complex obeys the Beer-Lambert Law.
Calculate the mass percentage of the cobalt in the original sample.
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