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Consider a buffer solution made from a partially neutralizing 1.00 M hydrochlorious acid (HClO, Ka=3.5*10^-8) with 0.500M sodium hydroxide.
A) Calculate the amount of base needed to make a buffer from 50.0mL of HClO with a pH equal to the pKa of the acid.
B) What is the pH of a buffer solution made in (a) after diluting to 500mL.
C) Which solution made in (a) or (b) will have a lower capacity if equal volumes of each are compared? Why ?
D) Calculate the pH of a buffer made using 30.0mL of the acid and 10.0mL of the base.
E) Calculate the pH of a buffer using 20.0ml of acid and 30.0mL of base.
F) Which solution made in (d) or (e) can buffer more acid ? Which can buffer more base? Why?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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