Calculate delta h and delta s and delta g

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water vapor can be maintained at 100 oC and 2 atm pressure for a time; it will spontaneously revert to a liquid. calculate delta H, delta S, delta G for g->l. Assume vapor behaves ideally and liquid is basically imcompressible. This is equivalent to assuming the equation of state for the liquid phase is Vm=.000018exp(.0002*(T-100)*exp(-4.6e-10*P). Vm is the molar volume of the liquid water. Hints: first get delta G using an appropriate 3 step path. Then get the other quantites from delta H: (d delta_G/dT|P)=delta_S; delta_H=delta_G-delta(TS)=delta_G-Tdelta_S.

Reference no: EM13337358

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