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To confirm the identity of the alkyl halide synthesized in this reaction, the product was subjected to two qualitative tests which distinguish between primary, secondary and tertiary halides. In the first, the product reacts with alcoholic silver nitrate to produce an insoluble salt whose color reflects the halide ion it contains. In the second, alkyl chlorides or bromides form an insoluble salt when they react with sodium iodide in acetone.
a. Write a mechanism for the reaction of an alkyl halide with alcoholic silver nitrate which depicts the type of substitution which occurs. Explain how this mechanism accounts for the relative rate of reactivity of primary, secondary and tertiary halides in this reaction
To this vessel 8.6787g of Ne are added in such a way that no butane escapes. The total pressure of the vessel (at the same temperature) is 1420 torr. Calculate the volume of the vessel and the mass of the butane.
what is the concentration of (HOCl), at equilibrium if 0.0230 mol of H2 and 0.0230 mol of ClO2 are initially placed in a 5 L vessel? What is the concentration of ClO2 in the above problem at equilibrium?
A student mixed 5.00 mL of a nickel(2) chloride solution with 5.00 mL of .100M sodium phosphate and a precipitate formed. How many moles of sodium phospahte were present in 5.00 mL of the solution?
what is the final temperature of this water/ethanol mixture? (Note: Assume there are no chemical interactions between the water and the ethanol that affect the temperature.)
A 32.22 g sample of a metal that looks like aluminum is heated to 99.8 C in hot water. The metal is then quickly transferred into exactly 50.0 ml of water at 22.9 C in a calorimeter
The antifreeze in a car was a 50% by weight solution of ethylene glycol C2H6O2 in water. Calculate the boiling point and freezing point of this solution. (for H2O: Kb= 0.52 C/m... Kf=1.86 C/m
Following a terrorist release of Cesium-137 (half-life of 30 years) in downtown, clean up efforts were successful in removing all but 100 curies. How long will it take for the contamination to decay to about 5 curies?
A 28.0-g sample of nitrogen gas combines completely with 6.0 of hydrogen gas to form ammonia. What is the mass of ammonia formed.
Maleic acid is a carbon-hydrogen-oxygen compound used in dyeing and finishing fabrics and as a preservative of oils and fats. In a combustion analysis, a 1.054- sample of maleic acid yields 1.599 of and 0.327 of.
Determine the pressure inside a container of a gas connected to an open-end manometer filled with CCl4, has the density = 1.594 g/cm3,
suppose a student attempts to do an ion exchange on a column that is already nearly saturated with CO2+ and Zn2+.
Quinine (C20H24N2O2) is the most important alkaloid derived from cinchona bark. It is used as an antimalarial drug.
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