Inductive effect - relative reactivity of aldehydes and keto, Chemistry

Assignment Help:

Inductive effect - Relative reactivity of aldehydes and ketones

The comparative re-activities of aldehydes and ketones in nucleophilic addition reactions might be attributed to the amount of positive charge on the carbon. As a higher positive charge seems a higher reactivity. Determine if the positive charge is detached throughout the molecule, the carbonyl compound turns out to be much more stable and its reactivity decreases. Here now, alkyl set is an electron releasing group (+I inductive effect). Hence, electron releasing energy of two alkyl groups in ketones is much more than that of one alkyl set in aldehyde. Since a product, the electron deficiency of carbon atom in the carbonyl group is satisfied much more in ketones as compared to in aldehydes. Hence, the replaced positive charge on carbon in case of ketones discourages the attack of nucleophiles. Therefore ketones are minimum reactive as compared to aldehydes. Formaldehyde correlated to no alkyl sets is the most reactive of the aldehydes and ketones. So, the order of reactivity is:

399_Inductive effect.png


Related Discussions:- Inductive effect - relative reactivity of aldehydes and keto

What do you mean by dative covalent bonds, Q. What do you mean by Dative Co...

Q. What do you mean by Dative Covalent Bonds?Dative Covalent Bonds Ans. Sometimes both electrons in the shared pair come from one atom. This type of bond is called a dativ

Explain cesium fluoride, Explain cesium fluoride Compound (2), cesium f...

Explain cesium fluoride Compound (2), cesium fluoride, would be most likely to exist as an ionic species, due to Cs and F come from opposite corners of the periodic table.

Dyes, Conditions which a dye must satisfy and describe them

Conditions which a dye must satisfy and describe them

Molecular mass and atomic mass of sulphur & atomicity, If molecular mass an...

If molecular mass and atomic mass of sulphur are 256 and 32 respectively, its atomicity is: (1) 2        (2) 8         (3 )4        ( 4)16 Ans: 8

What is the dipole moment of chloro-octane, What is the dipole moment of ch...

What is the dipole moment of chloro-octane? Ans) There are many forms of the molecule "chloro-octane." This is due to the chlorine atom can be attached to the octane chain in va

Separation techniquics using solute and solvent, suppose n mmol of solute A...

suppose n mmol of solute A in Vaq ml of aqueous solution is extracted with Vorg ml of animmiscible organic solvent. at equilibrium n1 mmol of A will remain in the aqueous layer and

What are the characteristics of bases, Q. What are the characteristics of b...

Q. What are the characteristics of bases? Ans. Common bases are borax, baking soda, and antacids. These are some characteristics of bases: They taste bitter

Conductance and conductivity, Conductance and conductivity: When a fiel...

Conductance and conductivity: When a field (electric) is put across an aqueous ionic solution by applying a voltage between two parallel plate electrodes, the cations are attra

Electrodic potential, calculate the electrode potential of a platinum elect...

calculate the electrode potential of a platinum electrode immersed in a solution containing Ce4 + ions (cCe4 + = 0.05M) and Ce3 + ions (cCe3 + = 0.1M)

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd