Inductive effect - relative reactivity of aldehydes and keto, Chemistry

Assignment Help:

Inductive effect - Relative reactivity of aldehydes and ketones

The comparative re-activities of aldehydes and ketones in nucleophilic addition reactions might be attributed to the amount of positive charge on the carbon. As a higher positive charge seems a higher reactivity. Determine if the positive charge is detached throughout the molecule, the carbonyl compound turns out to be much more stable and its reactivity decreases. Here now, alkyl set is an electron releasing group (+I inductive effect). Hence, electron releasing energy of two alkyl groups in ketones is much more than that of one alkyl set in aldehyde. Since a product, the electron deficiency of carbon atom in the carbonyl group is satisfied much more in ketones as compared to in aldehydes. Hence, the replaced positive charge on carbon in case of ketones discourages the attack of nucleophiles. Therefore ketones are minimum reactive as compared to aldehydes. Formaldehyde correlated to no alkyl sets is the most reactive of the aldehydes and ketones. So, the order of reactivity is:

399_Inductive effect.png


Related Discussions:- Inductive effect - relative reactivity of aldehydes and keto

Organic chemistry, the measured dipole moment of-para nitroaniline (6.2D) i...

the measured dipole moment of-para nitroaniline (6.2D) is larger than the value calculating using empirical group moment (5.2D)

Unity of hardnes, write the different units of hardness with their relatio...

write the different units of hardness with their relationship

Periodic table, solubility of s-block elements to flame test

solubility of s-block elements to flame test

Miller indices of the diagonal plane of a cube, Miller indices of the diago...

Miller indices of the diagonal plane of a cube are   (110)

Acid-base titrations - types of titrations, Acid-base titrations - Types of...

Acid-base titrations - Types of titrations While the strength of an acid is determined along with the help of a standard solution of base, it is termed as acidimetry. Similarly

Electrochemistry, Explain construction & working of calomel electrode.

Explain construction & working of calomel electrode.

Chemical Equilibrium, why is the reaction mixture does not have 50% reactan...

why is the reaction mixture does not have 50% reactants and 50% products?

Hybrisation, examples of spd arrangement

examples of spd arrangement

Sodium atom the number of electrons, For sodium atom the number of electron...

For sodium atom the number of electrons with m=0 will be: (1) 2        (2) 27      (3) 9          (4) 8 Ans: 7

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd