Find the value of limiting molar conductivity, Chemistry

Assignment Help:

(a) Describe how you would carry out a series of experiments to determine the molar conductivities (Λm) of an electrolyte at various concentrations, starting with the measurement of conductance.  Explain clearly how you would calibrate the apparatus to obtain the cell constant, and how you would use this value in your calculations.

(b) Explain briefly how you would plot the data obtained from the experiments in part (a) graphically to find the value of the limiting molar conductivity (Λm0) of:

(i)  a strong electrolyte;

(ii) a weak electrolyte.

(c) The molar conductivity of aqueous potassium perchlorate at 298K has been measured at selected concentrations:

 

c /mol dm-3

 

0.0005

 

0.0050

 

0.0200

 

0.0500

 

0.1000

 

Λm /S m2 mol-1

 

0.0139

 

0.0134

 

0.0128

 

0.0122

 

0.0115

(i) By means of a suitable graph, estimate the limiting molar conductivity (Λm0) of aqueous potassium perchlorate.

(ii) If the limiting molar ionic conductivity (λ-) of the perchlorate ion is 6.85 x 10-3  S m2 mol-1, calculate that of the potassium ion (λ+).


Related Discussions:- Find the value of limiting molar conductivity

An e - has magnetic quantum number, An e - has magnetic quantum number as 3...

An e - has magnetic quantum number as 3, what is its principal quantum number: (1) 1        (2) 2    (3) 3            (4) 4 Ans: 4

0 order, radioactive decay order

radioactive decay order

S block elements, Ask question #Minimum 100 what is sodium pump words accep...

Ask question #Minimum 100 what is sodium pump words accepted#

D-bock elements, color formation of d-block elements

color formation of d-block elements

#Equivalent weight, #how do i know the factor of a compound when getting it...

#how do i know the factor of a compound when getting its equivalent weight?

Synthetic detergents - oils and fats, Synthetic Detergents - Oils and Fats ...

Synthetic Detergents - Oils and Fats The synthetic Syndets or detergents are substitutes of soaps. They comprise cleansing power as good or better as compared to ordinary soaps

Photon absorption for ir spectroscopy, Photon absorption for IR spectroscop...

Photon absorption for IR spectroscopy                                                                  Photon absorption for IR spectroscopy

What are ferrites, What are ferrites? Ferrites are ceramic compounds c...

What are ferrites? Ferrites are ceramic compounds containing trivalent metal having three valence electrons, iron and oxide of divalent element i.e. metals having two free ele

Find the d-orbital splitting, In order to find the d-orbital splitting in a...

In order to find the d-orbital splitting in a square planar complex, it is easier to start with an octahedral compound where splitting patterns are known and then imagine slowly m

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd