Explain cycloaddition reaction, Chemistry

Assignment Help:

This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other.  Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition.  The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process.  In either case, the product has the following stereochemistry:

 

827_chemistry.png


Related Discussions:- Explain cycloaddition reaction

#title., biography on Cecil E Boord

biography on Cecil E Boord

Be2+ is isoelectronic with, Be 2+ is isoelectronic with: (1) Mg 2+    ...

Be 2+ is isoelectronic with: (1) Mg 2+                               (2) Na +    (3) Li +                    (4) H + Ans: Li +

Radiometric titration, principle and explanation of radiometric titration

principle and explanation of radiometric titration

Electronegative atom on the strength of ionic bond, What is the effect of m...

What is the effect of more electronegative atom on the strength of ionic bond: (1) Decreases (2) Increase (3) Decreases slowly (4) Remains the same Ans:  Increase

Grahams law, At 350 degrees C, nitrogen has a velocity of 800m/s. Find the ...

At 350 degrees C, nitrogen has a velocity of 800m/s. Find the velocity of hydrogen at the same temperature

Illustrate important catalyst of aluminium, Q. Illustrate important catalys...

Q. Illustrate important catalyst of aluminium? Anhydrous AlCl 3 is an important catalyst, used in organic synthesis and in the cracking of petroleum. Al 2 (S0 4 ) 3 as such o

Hyperconjugation, can i know the applications or the effects of hyperconjug...

can i know the applications or the effects of hyperconjugation on carbenes and nitrenes

Ionisation energy, does ionization energy ddepends on principal quantum n...

does ionization energy ddepends on principal quantum number

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd