A halogen addition reaction is a simple chemical reaction where a halogen molecule is added to the carbon-carbon double bond at an alkene functional group.

The common chemical formula of the halogen addition reaction is:

C=C + X₂ → X-C-C-X

(X stand for the halogens bromine or chlorine, and in this case, a solvent can be CH₂Cl₂ or CCl₄). The resultant product is a vicinal dihalide.

This sort of reaction is a halogenation and an electrophilic addition.

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