The Fries rearrangement, named after the German chemist Karl Theophil Fries, is a rearrangement reaction of a phenyl ester to a hydroxy aryl ketone through catalysis of Lewis acids.
It includes migration of an acyl group of phenyl ester to benzene ring. The reaction is ortho and para selective and one of the two products may be favoured by varying reaction conditions, like temperature and solvent.
Mechanism
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