A dyotropic reaction in organic chemistry is a kind of organic reaction and more specially a pericyclic valence isomerization in which two sigma bonds at the same time migrate intramolecularly. The reaction type is of some significance to organic chemistry as it can explain how certain reactions takes place and as it is a synthetic tool in the synthesis of organic molecules for instance in total synthesis. It was first explained by Manfred T. Reetz in 1971.
In a type I reaction two migrating groups exchange their relative positions and a type II reaction includes migration to new bonding sites with no positional interchange.
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