The Benary reaction is organic chemical reaction. In 1931 Erich Bénary found that β-(N,N-dialkylamino)-vinyl ketones reacted with Grignard reagents in a 1,4-addition to produce α,β-unsaturated aldehydes, α,β-unsaturated ketones and α,β-unsaturated esters and also poly-unsaturated ketones and aldehydes after hydrolysis of the reaction intermediate and removal of a dialkylated amine.
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