Acylation also known as alkanoylation is the method of adding an acyl group to a compound. The compound giving the acyl group is known as the acylating agent.
As they form a strong electrophile when reacted with some metal catalysts, acyl halides are generally used as acylating agents. For example, Friedel-Crafts acylation takes acetyl chloride (CH3COCl), as the agent and aluminum chloride (AlCl3) as a catalyst to put an ethanoyl (acetyl) group to benzene:
The mechanism involved in this reaction is electrophilic substitution.
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