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The coordination number of Ni in the complex is 4, the configuration of Ni+2 , at first sight, shows that the complex is formed by sp 3 hybridization and it is paramagnetic and it has two unpaired electrons. However, experiments show that the complex is diamagnetic, i.e. it do not have unpaired electrons, this is possible when 3d electrons rearrange against the hund's rule as shown in the below configuration. This is also in accordance with the fact that the ligand involved here is a strong i.e. CN- ion.Hence now dsp2 hybridization, involving one 3d, one 4s and two 4p orbitals, takes place leading to four dsp2 hybrid orbitals, each of which accepts four electron pairs from CN- ion forming
[Ni (CN4)] 2 ion. Thus the resulting complex is square planar and is diamagnetic as it has no unpaired electrons.
What are the compositions of the equilibrated top Layers? Figure is a temperature-composition phase diagram for the binary system of water (A) and phenol (B) at 1 bar. These li
Rayon - Semi Synthetic Polymers Rayon is a man made material which contains purified cellulose in the type of long fibres. Cellulose is reacted along with cold NaOH solution to
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what is the theoretical background of the topic?
what is meant by abnormal molecular mass of solute ? discuss the factors which bring abnormality in the experimentally determined molecular masses of solutes using colligative prop
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what are the differences between positive and negative mesomeric effect
#question.synthesis , postad date 1/12/2013, australia
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