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The order of a reaction is occasionally changed by conditions. Consider a chemical reaction between two substances where one reactant is there in large excess. During the hydrolysis of 0.01 mol of ethyl acetate with 10 ml of water, amounts of the various constituents at the beginning (t = 0) and complexion (t) of the reaction are given as under The concentration of water does not get altered much during the course of the reaction. So, in the rate equation Rate = k’ [CH3COOC2H5] [H2O] The term [H2O] can be taken as constant. The equation, thus, becomes Rate = k [CH3COOC2H5] Where k = k’ [H2O] And the reaction behaves as first order reaction. Such reactions are called pseudo first order reaction. Conversion of cane sugar is one more pseudo first order reaction. Rate = k [C12H22O11]
Types of titrations - Volumetric analysis Titrations can be categorized as : (A) Acid base titrations or alkalimetry and acidimetry (B) Redox titrations or Oxidation redu
The charge on the atom containing 17 protons, 18 neutrons and 18 electrons is: (1) +1 (2) -2 (3) -1 (4)Zero Ans: -1
The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state with an increase in temperature. This can be monitored by measurin
how yield of ether is highest when the halide ion is displased from a primary rather than secondary or tertiary halide?
Which electronic configuration is not observing the ( n+ 1) rule: (1) 1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 6 , 3d 1 , 4s 2 (2) 1s 2, sp 2 , sp 6 , 3s 2 , 3p 6 , 3
Classification of Coordination Compounds Since the number of known complexes is so large, we need to classify and categorise them in order to study their chemistry systematica
Q. Explain the structure of Alkenes? Ans. Alkenes have the general formula C n H 2n . Therefore, for every n carbon atoms, there are 2n hydrogen atoms. Alkenes have C =
Rutherford's alpha particle scattering experiment eventually led to the conclusion that: (1)The point of impact with matter can be precisely determined (2)Electrons occupy s
In a potassium atom, electronic energy levels are in the following order: (1) 4s>3d (2) 4s>4p (3) 4s (4) 4s Ans: 4s
Q. Explain about Coordination Isomerism? Coordination Isomerism: If the complex is a salt having both cation and anion as complex ions then the ligands can exchange position
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