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The order of a reaction is occasionally changed by conditions. Consider a chemical reaction between two substances where one reactant is there in large excess. During the hydrolysis of 0.01 mol of ethyl acetate with 10 ml of water, amounts of the various constituents at the beginning (t = 0) and complexion (t) of the reaction are given as under The concentration of water does not get altered much during the course of the reaction. So, in the rate equation Rate = k’ [CH3COOC2H5] [H2O] The term [H2O] can be taken as constant. The equation, thus, becomes Rate = k [CH3COOC2H5] Where k = k’ [H2O] And the reaction behaves as first order reaction. Such reactions are called pseudo first order reaction. Conversion of cane sugar is one more pseudo first order reaction. Rate = k [C12H22O11]
Glucose and fructose are epimers so they are differ in their second carbon position and remaining is same so when they react with phenylhydrazeen they give same osazone
theory of the acidic and basic radicals in different chocolates
Types of interferences - Atomic absorption spectrophotometry: Three types of interferences viz., chemical, spectral and physical interferences are encountered in AAS. These re
Baeyer's reagent - Tests of unsaturation It is 1% solution consisting of sodium carbonate. It is of pink in colour. An aqueous solution of the element, some drops of Baeyer's
State 2nd law of thermodynamics in many forms as possible and show that they are identical in figures?
formation of scales
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Benzene is a very symmetrical compound Benzene is a very symmetrical compound. The carbon framework is essentially a planar hexagon. Because of its resonance structures, all car
what is the name of the precipitate and the formulae of the precipitate of NH3 (aq) and Pb(NO3)2 (aq)
Upon treatment of A with benzyl amine in the presence of a weak acidic catalyst, they obtained mainly the undesired amino alcohol C along with some of the desired product D that c
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