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What is Frenkel defect
A pair of one cation and one anion can be missing from an ionic crystal as shown in the following figure. Such a pair of vacant sites is called Schottky defects. Also, in ionic crystals, an ion displaced from a regular site to an interstitial site is called Frenkel defect. As cations are generally the smaller in size, it is possible for them to get displaced into void space. A Frenkel defect does not change the overall electrical neutrality of the crystal. These types of defect are dominant in alkali halides.
The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state with an increase in temperature. This can be monitored by measurin
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Fe(atomic number = 26) atom has the electronic arrangement: (1) 2, 8, 8, 8 (2) 2, 8, 16 (3) 2, 8,14, 2 (4) 2, 8, 12, 4 Ans: 2, 8,14, 2
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