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THermodynamic free enrgy is the amount of work a thermodynamic system can perform. The concept is useful in the thermodynamics of chemical or thermal processes in engineering and science. The free energy is the internal energy of a system minus the amount of energy that cannot be used to perform work. This unusable energy is given by the entropy of a system multiplied by the temperature of the system.Like the internal energy, the free energy is a thermodynamic state function.
Chemical nature
The second law states that where dS ≥ dQ/T for a reversible process and dS = dQ/T for an irreversible process. a. Show that since dW 12 = -dW 21 (dW reverse = -dW forwar
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