The band model, Chemistry

Assignment Help:

The band model of solids is an extended of the molecular orbital (MO) method. The overlap of atomic orbitals in an extended solid produces rise to continuous bands of electronic energy levels associated with different degrees of bonding. In a simple monatomic solid the bottom of the band is build up of orbitals bonding between all neighboring atoms; orbitals at the top of the band are antibonding, and levels in the middle have an intermediate bonding character. Different atomic orbitals may, in principle, give rise to different bands, although they may overlap in energy.

 

 

 

1262_Untitled.png

 

Fig. 1. Band picture for (a) nonmetallic and (b) metallic solid; occupied electronic levels are shown shaded.

 

Increases in temperature approximately in accordance with the Arrhenius equation used in chemical kinetics.

 


Related Discussions:- The band model

F-Block, why is the f-block grouped in the way it is

why is the f-block grouped in the way it is

What do you mean by blanching, Q. What do you mean by Blanching? The en...

Q. What do you mean by Blanching? The enzymes in the food system can be separated into four groups relating to the changes in flavour, colour, texture and nutritive value. T

Semicoducting polymers, mathematical expression for conductivity of polyme...

mathematical expression for conductivity of polymers

Define recipe problem in experimental design method, Define Recipe problem ...

Define Recipe problem in experimental design method Recipe is one of the most important factors leading to successful food products. A recipe usually includes several ingredie

Qualatative annalysis, Why wet test not perform for some acid radicals ?

Why wet test not perform for some acid radicals ?

Calculate hybridisation of an atom, I want to know how to calculate hybridi...

I want to know how to calculate hybridisation of an atom in a given compound like I want to calculate hybridisation of Boron & Oxygen in this boric acid compound H 3 BO 3 I even w

Electronic displacement in covalent bonds, Electronic displacement in coval...

Electronic displacement in covalent bonds It is examined that most of the attacking reagents all time possess either a positive or a negetive charge, hence for a solution to op

The structure of spiropentadiene, The structure of spiropentadiene The ...

The structure of spiropentadiene The structure of spiropentadiene is shown below; it undergoes a Diels-Alder reaction with two molar equivalents of 1,3-cyclopentadiene. Spirope

Explain cmr spectrum, Explain CMR spectrum 2,2-Dimethyl-1-propanamine (...

Explain CMR spectrum 2,2-Dimethyl-1-propanamine (neopentylamine, (CH 3 ) 3 CCH 2 NH 2 ) has a maximum of three resonances in its CMR spectrum.  2-Methyl-2-butanamine, CH 3 CH 2

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd