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The abstraction of a hydrogen atom
The H-CN bond is stronger than the O-H bond, the abstraction of a hydrogen atom from HCN by the tert-butoxy radical is endothermic by 528 - 438 = 90 kJ mol-1. (These numbers are from Table 5.3 with the bond energy of CH3O-H as an approximation for that of (CH3)3CO-H.) The first initiation step, formation of the tert-butyloxy radical from a peroxide, is also endothermic. Because both initiation steps are highly endothermic, the reaction is not likely to generate a high enough concentration of radicals to initiate a chain reaction.
Preparation of chemical reagents I. Purpose of the Experiment A reagent is any substance in a chemical reaction. Different reagents are used for laboratory experiments
What is meant by ''mass number''
Here''s the equation: NaOH + H2SO4 = Na2SO4 + H2O
two reasons why is it necessary to ionise chromium atomsin a sample
Methylated spirits burner A easy burner can be made from an old boot polish tin. Though it is not necessary, a metal tube can be soldered to the top and a twisted piece of wire
Physical properties of nitroalkanes
Explain the properties of ionic bonding
why pcl3 is less polar than sicl4
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Classification of polymers Classification lies on source of availability: They are categorized as (a) Natural polymers (b) Synthetic polymers
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