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The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state with an increase in temperature. This can be monitored by measuring magnetic moments. Predict the spin-only magnetic moment, in Bohr magnetons, that you would expect for each spin state.
An aqueous solution of cobalt (III) is diamagnetic. In the presence of excess fluoride ion, the above cobalt solution becomes paramagnetic. Use CFT arguments to give an explaination for this observation.
NiCl42- responds strongly to an external magnetic field while NiCN42- responds barely at all.
Explain how this information can be used to show that the two complexes possess differing geometries for their ligands about the metal center.
The complex Cr(H2O)63+ has high symmetry (Oh) while the complex Cu(H2O)62+ is seen to adopt lower symmetry ( D4h). Give an explaination for this observation.
The quantum numbers for the outermost electron of an element are given below as n= 1, l=0, m=0, s = 1/2 . The atoms is: (1) Lithium (2) Beryllium (3) Hydrogen (4)
Iodide ion is a good nucleophiles Because iodide ion is a good nucleophiles and the trimethyloxonium ion is an good alkylating agent, alkylation of the iodide ion occu
Sharp line source: When the bandwidth of the primary radiation is low with respect to the profile of the analyte absorption, the given amount of analyte would absorb more radi
Attacking Reagents - Organic chemistry The fission of the substrate molecule to make centres of high or low electron density is affected by attacking reagents. Most of the atta
application of electromeric effect
Which one is the electronic configuration of Fe +2 : (1) 1s 2, 2s 2 , 2p 6 , 3s 2 , 3p 6 , 3d 6 (2) 1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 4 , 4s 2 (3) 1s 2 , 2s 2 ,
the properties of s,p,d,f block elements?
Nucleophilic addition reactions (i) Carbonyl compounds give nucleophilic addition reaction along with those reagents which on dissociation give electrophile also nucleophile.
explain Fischer diagram
positve deviation from beer''s law
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