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The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state with an increase in temperature. This can be monitored by measuring magnetic moments. Predict the spin-only magnetic moment, in Bohr magnetons, that you would expect for each spin state.
An aqueous solution of cobalt (III) is diamagnetic. In the presence of excess fluoride ion, the above cobalt solution becomes paramagnetic. Use CFT arguments to give an explaination for this observation.
NiCl42- responds strongly to an external magnetic field while NiCN42- responds barely at all.
Explain how this information can be used to show that the two complexes possess differing geometries for their ligands about the metal center.
The complex Cr(H2O)63+ has high symmetry (Oh) while the complex Cu(H2O)62+ is seen to adopt lower symmetry ( D4h). Give an explaination for this observation.
The known metal ion solution used contains 0.10 M of each of the six metal ions (i.e. 0.10 M Ag+ and 0.10M Pb2+). An equal volume of 3 M HCl and the known solution are mixed. What
Show that wavefunction ψ1(x) = (2/L) 1/2 sin(πx/L) of a particle in a box is an eigenfunction of the operator d 2 /dx 2 and also calculate the corresponding eigenvalue.
can i have some problems regarding law of conservation of mass
What will be wave length of a ball of 0.1 kg mass moving with 10 ms -1 velocity
Q. What is Atomic Mass Units? Ans. Notice in the last column of the table, the masses of the subatomic particles are reported in atomic mass units. The actual masses of electro
what is chemical arithmetic and solution?
reactivity of f-block elements
Write down the chemical equations for the total burning of propane and butane gas in air. Show whether the substances are liquid (l), gaseous (g), or solid (s) under
how to calculate the equivalent weight of an ion
What will be the mole fraction of 98% pure H2SO4 in 1 liter solution which has density 1.85gm/ml at ntp?
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