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The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state with an increase in temperature. This can be monitored by measuring magnetic moments. Predict the spin-only magnetic moment, in Bohr magnetons, that you would expect for each spin state.
An aqueous solution of cobalt (III) is diamagnetic. In the presence of excess fluoride ion, the above cobalt solution becomes paramagnetic. Use CFT arguments to give an explaination for this observation.
NiCl42- responds strongly to an external magnetic field while NiCN42- responds barely at all.
Explain how this information can be used to show that the two complexes possess differing geometries for their ligands about the metal center.
The complex Cr(H2O)63+ has high symmetry (Oh) while the complex Cu(H2O)62+ is seen to adopt lower symmetry ( D4h). Give an explaination for this observation.
Types of Substituents which Produce Directive Effect There are two kinds of substituents which generate directive effect are, (i) Those that direct the incoming group to ort
Q. Write phosphate conditioning method for water softening with suitable chemical reactions. How it is different from soda lime method. Ans. Phosphate condition
H2,Li2,B2 each has bond order equal to 1 , the order of stability is
i) Electrophillic substitution in case of aromatic amines takes place more readily than benzene. ii) Nitro compounds have higher boiling points than hydrocarbons having almost s
maxmium 500 words
Beilstein test or copper wire test - Halogens A clean copper wire is heated in the Bunsen flame till it does not impart any type of green colour to the flame. The heated side
what is the class of HS
diagrams of f orbitals
Q. Describe Linkage Isomerism? Some ligands can coordinate to the metal through different donor ato...s present in the ligand. They are called ambidentate ligands and they can
Sphere packing Element structures where chemical bonding is nondirectional are best explained by considering the packing of equal spheres. Close-packed structures are on
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