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The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state with an increase in temperature. This can be monitored by measuring magnetic moments. Predict the spin-only magnetic moment, in Bohr magnetons, that you would expect for each spin state.
An aqueous solution of cobalt (III) is diamagnetic. In the presence of excess fluoride ion, the above cobalt solution becomes paramagnetic. Use CFT arguments to give an explaination for this observation.
NiCl42- responds strongly to an external magnetic field while NiCN42- responds barely at all.
Explain how this information can be used to show that the two complexes possess differing geometries for their ligands about the metal center.
The complex Cr(H2O)63+ has high symmetry (Oh) while the complex Cu(H2O)62+ is seen to adopt lower symmetry ( D4h). Give an explaination for this observation.
Q. Isomerism in Coordination Compounds? You have already learnt about isomerism in your earlier studies. The phenomenon of isomerism is not restricted to organic compounds only
Prepare an assignment on the topic commercial cells
can all the total heat content available betotally converted to work done?
Calculate the energy required to compress carbon dioxide from 1 bar to 50 bar (final volume is 50 ml, 298 K, ideal gas).
A hydrocarbon z with molecular mass 78 on combustion gave 3.384g of carbon (IV) oxide and 0.693g of water. Determine the molecular formula of Z and draw its structure. [H=1, C=12,
The complete explanation
When 100 ml of M/10 H2SO4 is mixed with 500 ml of My/10 NaOH then nature of resulting solution and normality of excess reactant left is
Valence electron of pd Pd has ten valence electrons in the neutral atom. There are no charges and no X-type ligands in the complex; as, this is a d 10 complex.
Reactions involved in salt analysis
What kind of relation is there between them and the force constants of vibration that you have calculated? The enthalpies of vaporization of carbon and silicon are 717 kJmol -1
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