Spin-only magnetic moment, Chemistry

Assignment Help:

The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state  with an increase in temperature.  This can be monitored by measuring magnetic moments.  Predict the spin-only magnetic moment, in Bohr magnetons, that you would expect for each spin state.

2015_ion.png

An aqueous solution of cobalt (III) is diamagnetic.  In the presence of excess fluoride ion, the above cobalt solution becomes paramagnetic.  Use CFT arguments to give an explaination for this observation.   

NiCl42- responds strongly to an external magnetic field while NiCN42- responds barely at all.

Explain how this information can be used to  show that the two complexes possess differing geometries for their ligands about the metal center.

The complex Cr(H2O)63+ has high symmetry (Oh) while the complex Cu(H2O)62+ is seen to adopt lower symmetry ( D4h).  Give an explaination for this observation.


Related Discussions:- Spin-only magnetic moment

Electrolysis laws by michael faraday., electrolysis laws by michael faraday...

electrolysis laws by michael faraday and how they helped him to find particle nature of electricity??

What are galvanic cells and explain its working?, The device through which ...

The device through which chemical energy is converted into electrical energy is known as galvanic cell or electrochemical cell or voltaic cell. In a galvanic cell, a redox reaction

Electrochemistry, Electrocatalysis is a branch of electrochemistry dealing ...

Electrocatalysis is a branch of electrochemistry dealing with anodically and cathodically induced radical reaction mechanisms utilizing the electrochemical reactivity of an organom

What is aronatic compounds ?, Aromatic compounds are compounds having one o...

Aromatic compounds are compounds having one or more benzene rings in it . These compounds satisfies the huckel''s rule. Huckel''s rule:- Compounds contain 4n+2 pi electrons are ar

Differences in between the mixtures and compounds, Explain the mixtures and...

Explain the mixtures and compounds   Mixture Compound 1.      Mixtures are made from 2 or more substances which are not chemically co

Types of substitution reactions - organic reactions, Types of substitution ...

Types of substitution reactions According to the type of the nature of attacking species substitution reactions are categorized into following three categories, (A) Nucleoph

Covalent bonding, Give ten Characteristics of convalent bonding

Give ten Characteristics of convalent bonding

Molecular formula, Molecular Formula Molecular formula of a substanc...

Molecular Formula Molecular formula of a substance provides the actual number of atoms that present in one molecule of the substance. Molecular formula = n * Empirical fo

Explain stereochemistry, Explain stereochemistry a) The stereochemistry...

Explain stereochemistry a) The stereochemistry is E. The Br has higher priority on one carbon stereocenter, but it has lower priority on the other. b) The stereochemistry is

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd