Redox Titration, Chemistry

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What is the reliablitiy of redox titrations?

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If electron falls from n=3  to n= 2 , then emitted energy is: (1) 10.2ev                            (2) 12.09 ev           (3) 1.9ev                              (4)0

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This is an acid-catalyzed addition to the double bond much like hydration, except that an alcohol rather than water is the nucleophile that reacts with the carbocation intermediate

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