How tetrahedral complex splitting takes place?, Chemistry

Assignment Help:

The tetrahedral arrangement of four ligands surrounding the metal ion may be visualized. It is clear that in tetrahedral field, none of the orbitals point exactly towards the ligands and therefore, the splitting of energy will be less that in octahedral field. The tree d-orbitals dxyand dyz and dzx are pointing close to the direction in which the ligands are approaching while the two orbitals  244_Untitled.png  and  942_Untitled.png  are lying in between the ligands. Therefore, the energies of the three orbitals will be raised while the energies of the two orbitals will be lowered. Thus, in the presence of octahedral field, the degeneracy of five d-orbitals splitting as:
    
The two orbitals,  244_Untitled.png  and  942_Untitled.png  becomes stable and their energies are lowered. These are designated as 'e' orbitals.
    
The three orbitals, dxy, dyz and dzx become unstable and their energies are raised. These are designated as 't2' orbitals. 

The magnitude of crystal field splitting is the difference between e and t2 orbitals and is designated as Δt, (the subscript indicating tetrahedral complexes). It is also measured in terms of Dq and Δt, = 10 Dq. If we compare the magnitude of crystal field splitting in octahedral and tetrahedral complexes (having same metal ion, ligands and metal ion-ligand distances), it has been observed that the crystal field splitting in octahedral complexes t) is considerably less than in octahedral complexes 0). It has been found to be Δt = 4/9 Δ0.

There are two main reasons for the smaller value of crystal field splitting in tetrahedral than in octahedral complexes.
    
In tetrahedral complexes there are four ligands while there are six ligands in octahedral complexes. Therefore, lesser ligands produce less crystal field splitting. The crystal field splitting in tetrahedral field is about two third of the octahedral field.
    
In tetrahedral field, none of the orbitals is pointing directly towards the ligands and, therefore, splitting is less.

Since the magnitude of crystal field splitting in tetrahedral field is quite small and is always less the pairing energy, therefore, the pairing of electrons will never be energetically favourable. Thus; all the tetrahedral complexes are high spin complexes. No tetrahedral complex with low spin has been found to exist. 

 

 

 


Related Discussions:- How tetrahedral complex splitting takes place?

#thermochemistr, can all the total heat content available betotally convert...

can all the total heat content available betotally converted to work done?

Determine nitrogen has the electronic configuration, Nitrogen has the elect...

Nitrogen has the electronic configuration  1s 2 , 2s 2 , 2p 1 x , 2p 1 y , 2 p 1 z   and not 1s 2 , 2s 2 , 2p 2 x , 2p 1 y , 2 p 0 z      which is determined by: (1) Aufb

Atomic structure, how ti find numbeer of neutrons in dipositive zinc ion wi...

how ti find numbeer of neutrons in dipositive zinc ion with mass number 70?

Catalysts, how a catalyst perform its work

how a catalyst perform its work

Explain production, Normal 0 false false false EN-US ...

Normal 0 false false false EN-US X-NONE X-NONE MicrosoftInternetExplorer4

Reversible cell, What things i can include under this topic(reversible cell...

What things i can include under this topic(reversible cell).

The highest melting point, Which of the following has highest melting point...

Which of the following has highest melting point: (1)  BaCl 2                                             (2)  MgCl 2               (3)  Cacl 2

Indicate the nature of bonding, Indicate the nature of bonding in CCl 4   a...

Indicate the nature of bonding in CCl 4   and  CaH 2 : (1) Covalent in Ccl 4    and electrovalent in  Cah 2 (2) Electrovalent in both CCl  and CaH 2 (3) Covalent in bot

How do we define the molecularity of a reaction, The number of species part...

The number of species participating in the slowest step of the reaction is known as molecularity of the reaction.

Heat Transfer Problems, 200 g of water at 30 degrees C is mixed with 20 g o...

200 g of water at 30 degrees C is mixed with 20 g of silver at 350 degrees C, what''s the final temp?

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd