How tetrahedral complex splitting takes place?, Chemistry

Assignment Help:

The tetrahedral arrangement of four ligands surrounding the metal ion may be visualized. It is clear that in tetrahedral field, none of the orbitals point exactly towards the ligands and therefore, the splitting of energy will be less that in octahedral field. The tree d-orbitals dxyand dyz and dzx are pointing close to the direction in which the ligands are approaching while the two orbitals  244_Untitled.png  and  942_Untitled.png  are lying in between the ligands. Therefore, the energies of the three orbitals will be raised while the energies of the two orbitals will be lowered. Thus, in the presence of octahedral field, the degeneracy of five d-orbitals splitting as:
    
The two orbitals,  244_Untitled.png  and  942_Untitled.png  becomes stable and their energies are lowered. These are designated as 'e' orbitals.
    
The three orbitals, dxy, dyz and dzx become unstable and their energies are raised. These are designated as 't2' orbitals. 

The magnitude of crystal field splitting is the difference between e and t2 orbitals and is designated as Δt, (the subscript indicating tetrahedral complexes). It is also measured in terms of Dq and Δt, = 10 Dq. If we compare the magnitude of crystal field splitting in octahedral and tetrahedral complexes (having same metal ion, ligands and metal ion-ligand distances), it has been observed that the crystal field splitting in octahedral complexes t) is considerably less than in octahedral complexes 0). It has been found to be Δt = 4/9 Δ0.

There are two main reasons for the smaller value of crystal field splitting in tetrahedral than in octahedral complexes.
    
In tetrahedral complexes there are four ligands while there are six ligands in octahedral complexes. Therefore, lesser ligands produce less crystal field splitting. The crystal field splitting in tetrahedral field is about two third of the octahedral field.
    
In tetrahedral field, none of the orbitals is pointing directly towards the ligands and, therefore, splitting is less.

Since the magnitude of crystal field splitting in tetrahedral field is quite small and is always less the pairing energy, therefore, the pairing of electrons will never be energetically favourable. Thus; all the tetrahedral complexes are high spin complexes. No tetrahedral complex with low spin has been found to exist. 

 

 

 


Related Discussions:- How tetrahedral complex splitting takes place?

Define elements and compounds, Q. Define Elements and Compounds? Pure s...

Q. Define Elements and Compounds? Pure substances are categorized into two categories that are elements and compounds. An element is a substance that can't be separated into

Fblock, similarity between later actinide and later actinide

similarity between later actinide and later actinide

IUPAC Naming, Could you please provide me the priority order of polyfunctio...

Could you please provide me the priority order of polyfunctional prefixes

Methods for manufacture of soaps, Methods for Manufacture of Soaps Ther...

Methods for Manufacture of Soaps There are the following three methods for manufacture of soaps: (a) The cold process (b) The hot process (c) Modern process

Explain combined gas law, Q. Explain Combined Gas Law? Ans. The  ...

Q. Explain Combined Gas Law? Ans. The  combined gas law  combines Boyle's law and Charles' law. The combined gas law describes situations where a gas undergoes simul

Unsaturated dicarboxylic acids, Unsaturated dicarboxylic acids The mole...

Unsaturated dicarboxylic acids The molecular formula of the simplest unsaturated dicarboxylic acid is HOOC.CH=CH.COOH This formula, however represents two chemical compounds, m

Wet test, what is the easy wet test of copper?

what is the easy wet test of copper?

Periodic table and periodicity of properties, alkali metals belong to s-blo...

alkali metals belong to s-block in the periodic table.why?

Caculate the molar mass of the solute, A solution is made by dissolving30 g...

A solution is made by dissolving30 g of a non-volatile solute in 90 g of water. It has a vapour pressure of 2.8 kPa at 298 K. At 298 K, vapour pressure of pure water is 3.64 kPa

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd