How tetrahedral complex splitting takes place?, Chemistry

Assignment Help:

The tetrahedral arrangement of four ligands surrounding the metal ion may be visualized. It is clear that in tetrahedral field, none of the orbitals point exactly towards the ligands and therefore, the splitting of energy will be less that in octahedral field. The tree d-orbitals dxyand dyz and dzx are pointing close to the direction in which the ligands are approaching while the two orbitals  244_Untitled.png  and  942_Untitled.png  are lying in between the ligands. Therefore, the energies of the three orbitals will be raised while the energies of the two orbitals will be lowered. Thus, in the presence of octahedral field, the degeneracy of five d-orbitals splitting as:
    
The two orbitals,  244_Untitled.png  and  942_Untitled.png  becomes stable and their energies are lowered. These are designated as 'e' orbitals.
    
The three orbitals, dxy, dyz and dzx become unstable and their energies are raised. These are designated as 't2' orbitals. 

The magnitude of crystal field splitting is the difference between e and t2 orbitals and is designated as Δt, (the subscript indicating tetrahedral complexes). It is also measured in terms of Dq and Δt, = 10 Dq. If we compare the magnitude of crystal field splitting in octahedral and tetrahedral complexes (having same metal ion, ligands and metal ion-ligand distances), it has been observed that the crystal field splitting in octahedral complexes t) is considerably less than in octahedral complexes 0). It has been found to be Δt = 4/9 Δ0.

There are two main reasons for the smaller value of crystal field splitting in tetrahedral than in octahedral complexes.
    
In tetrahedral complexes there are four ligands while there are six ligands in octahedral complexes. Therefore, lesser ligands produce less crystal field splitting. The crystal field splitting in tetrahedral field is about two third of the octahedral field.
    
In tetrahedral field, none of the orbitals is pointing directly towards the ligands and, therefore, splitting is less.

Since the magnitude of crystal field splitting in tetrahedral field is quite small and is always less the pairing energy, therefore, the pairing of electrons will never be energetically favourable. Thus; all the tetrahedral complexes are high spin complexes. No tetrahedral complex with low spin has been found to exist. 

 

 

 


Related Discussions:- How tetrahedral complex splitting takes place?

Electroanalytical technique, Electroanalytical technique: An electroan...

Electroanalytical technique: An electroanalytical technique is based on the measurement of one or more electrical quantities and their magnitudes could be correlated with the

Number of unpaired electrons, The number of unpaired electrons in Fe 3+ (Z...

The number of unpaired electrons in Fe 3+ (Z= 26)  are: (1) 5        (2) 6        (3) 3        (4) 4 Ans: 5

Dithizone-chelating agent, the reaction equations for the dissociation of d...

the reaction equations for the dissociation of dithzone into chelate anions and the formation of metal-dithizone chelates

S block elements, lithium and beryllium markedly differ from other members ...

lithium and beryllium markedly differ from other members of their respstive groups

Non-electrolyte solutions, NON-ELECTROLYTE SOLUTIONS Composition: ...

NON-ELECTROLYTE SOLUTIONS Composition: A solution is a mixture of two or more substance; this consists of one or more minority substances, the solute(s), dispersed in a ma

Structure of atoms, briefly explain laws of atoms with example

briefly explain laws of atoms with example

Valence electron of pd, Valence electron of pd Pd has ten valence elect...

Valence electron of pd Pd has ten valence electrons in the neutral atom.   There are no charges and no X-type ligands in the complex; as, this is a d 10 complex.

Explain generation of the electrophile, Generation of the electrophile : Th...

Generation of the electrophile : The electrophile is the carbocation produced by protonation of the alcohol  oxygen and loss of water.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd