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Explain the types of polymorphism
In terms of thermodynamics, there are two kinds of polymorphism. For a monotropic system, a plot of the free energy of the various polymorphs against temperature do not cross before all polymorphs melt--in other words, any transition from one polymorph to another will be irreversible. For an enantiotropy system, a plot of the free energy against temperature shows a crossing point before the various melting points, and it might be possible to convert reversibly among the two polymorphs on heating and cooling.
Determination of packing fraction of diamond The co-ordination number of an atom in diamond structure is 4 as can be seen from the unit cell of diamond and is loosely packed.
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