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Q. Explain about Hydrogen Sulphide?
Hydrogen sulphide is the only thermodynamically stable sulphane. It is a foul smelling and poisonous gas.
H2S is prepared in the laboratory by treating FeS with dilute HCI in Kipp's apparatus. In aqueous solution H, S is a weak acid. At 293 K, it dissociates as shown below:
You must have used H2S in qualitative identification and separation of cations. This separation is based on selective precipitation of the sulphides in acidic and alkaline medium: In the acidic medium, the ionisation of H2S which is a weak acid, is further suppressed and the solubility product of sulphides of relatively less soluble cations of Group 11, namely. Pb2+, Hg2+, Bi3+, Cu2+ , Cd2+ . As3+, Sb3+, Sn+2 is exceeded:
In Group IV, in the presence of ammonia, a higher concentration of S2- ions is obtained leading to the precipitation of the more soluble sulphides of Zn, Mn, Ni and Co.
Q. What is Peroxodisulphuric Acid? It is also known as perdisulphuric acid or simply persulphuric acid. The acid can be obtained by the action of chlorosulphonic acid on H 2 0
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If n= 3 , then the value of which is incorrect: (1) 0 (2) 1 (3) 2 (4)3 Ans: 3
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