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Q. Explain about Hydrogen Sulphide?
Hydrogen sulphide is the only thermodynamically stable sulphane. It is a foul smelling and poisonous gas.
H2S is prepared in the laboratory by treating FeS with dilute HCI in Kipp's apparatus. In aqueous solution H, S is a weak acid. At 293 K, it dissociates as shown below:
You must have used H2S in qualitative identification and separation of cations. This separation is based on selective precipitation of the sulphides in acidic and alkaline medium: In the acidic medium, the ionisation of H2S which is a weak acid, is further suppressed and the solubility product of sulphides of relatively less soluble cations of Group 11, namely. Pb2+, Hg2+, Bi3+, Cu2+ , Cd2+ . As3+, Sb3+, Sn+2 is exceeded:
In Group IV, in the presence of ammonia, a higher concentration of S2- ions is obtained leading to the precipitation of the more soluble sulphides of Zn, Mn, Ni and Co.
Explain the Systems at high pressure - Phase Diagram? Binary phase diagrams begin to look different when the pressure is greater than the critical pressure of either of the pur
Which of the following electron transition in a hydrogen atom will require the largest amount of: (1) From n-1 to n=2 (2) From n= 2 to n=3 (3) From n= ∞ to n=
The first ionization potentials for Na, K, and Rb are 5.138, 4.341, and 4.166 eV, respectively. Assume that the energy level of the outer electron can be represented by a hydrogenl
Anesthetics: It may be described as those drugs that generate insensibility to the major functions of all types of cell particularly of nervous system. Anesthetics may be categ
α -elimination reactions or 1,1-elimination reactions: A reaction where both the groups or atoms are removed from similar carbon of the molecule is called α - elimination reac
A reaction among sodium hydroxide and hydrogen chloride gas produces sodium chloride and water and a reaction of 22.85g of sodium hydroxide with 20.82g of hydrogen chloride gives o
It is important to differentiate the stoichiometric or empirical formula of a molecular substance from its molecular formula. The former expresses only the relative numbers of atom
K c is the equilibrium constants when the concentrations are expressed in moles/litre K c = Product of concentrate ions of products / product of concentrate ions of reactants
discuss importance of distribution ratio
introduction to chemical bonding
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