Explain about hydrogen sulphide, Chemistry

Assignment Help:

Q. Explain about Hydrogen Sulphide?

Hydrogen sulphide is the only thermodynamically stable sulphane. It is a foul smelling and poisonous gas.

H2S is prepared in the laboratory by treating FeS with dilute HCI in Kipp's apparatus. In aqueous solution H, S is a weak acid. At 293 K, it dissociates as shown below: 

740_Hydrogen Sulphide.png

You must have used H2S in qualitative identification and separation of cations. This separation is based on selective precipitation of the sulphides in acidic and alkaline medium:  In the acidic medium, the ionisation of H2S which is a weak acid, is further suppressed and the solubility product of sulphides of relatively less soluble cations of Group 11, namely.  Pb2+, Hg2+, Bi3+, Cu2+ , Cd2+ . As3+, Sb3+, Sn+2 is exceeded:

1988_Hydrogen Sulphide1.png

In Group IV, in the presence of ammonia, a higher concentration of S2- ions is obtained leading to the precipitation of the more soluble sulphides of Zn, Mn, Ni and Co.

73_Hydrogen Sulphide2.png


Related Discussions:- Explain about hydrogen sulphide

Atomic fluorescence spectrometry, Atomic fluorescence spectrometry: In...

Atomic fluorescence spectrometry: In atomic fluorescence spectrometry, the gaseous atoms acquired through flame or electrothermal atomisation are excited to higher energy leve

General arrangement of physical elements of a galvanic cell, Define the Gen...

Define the General Arrangement of Physical Elements of a Galvanic cell? The general arrangement of the physical elements of a galvanic cell is therefore Terminal - electron

#title.acetaldehyde and ketone., #uestion.. what is difference between acet...

#uestion.. what is difference between acetaldehyde and ketone

Aluminium used as a reducing agent of metals. why?, The free energy change...

The free energy change for the formation of oxide of aluminium is highly negative ( -1000 to -1100) so , it can easily reduce any metal oxide abve it easily in ellingham diamgram a

The strongest bond, Which one is the strongest bond: (1) Br- F    (2...

Which one is the strongest bond: (1) Br- F    (2)  F-E                             (3)  Cl-F                   (4)  Br- Cl Ans: Br- F

Find series of hydrogen atom spectrum electronic transition, In Balmer seri...

In Balmer series of hydrogen atom spectrum which electronic transition causes third line: (1) Fifth Bohr orbit to second one (2) Fifth Bohr orbit to first one (3) Fourth

Attaking reagent, what is attacking reagent/what its type give detail about...

what is attacking reagent/what its type give detail about this

Preparation of trimethyl, Preparation of 2,2,6-trimethyl-5-phenylheptan-3-o...

Preparation of 2,2,6-trimethyl-5-phenylheptan-3-one: Safety 2-Bromopropane : Irritating to eyes, respiratory system and skin. If eye contact, wash with large volumes of

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd