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Q. Explain about Coordination Isomerism?
Coordination Isomerism: If the complex is a salt having both cation and anion as complex ions then the ligands can exchange position between the cation and the anion. This will result in the formation of coordination isomers. Let us consider one such series:
[Co (en) 3][Cr(C2O4)3] Co(en)2 (C2O4)] [ Cr(en) (C2O4) 2]
[Cr(en)2(C2O4] [Co(en) (C2O4)2] [ Cr(en)3 (C2O4) 2]
It is possible to have the same metal ion present in both cationic and anionic species as shown by the following example:
[Cr (en)3[Cr(C204)3 and [Cr(en)2 (C204)I [Cr(en) (C2O4)2]
Note that in the above example both the oxidation state of the metal ion and its coordination number is same in the cation and anion. Let us consider yet another example where the above condition may be different:
[PII (NH3)4] [Ptiv Cl6 ]and [Ptiv(NH3)4 Cl2] [PtIICl4]
Dessicants(drying agents) can often be regenerated by heating. A dessicant that is commonly regenerated is CaSO 4 .2H 2 O:
The expression for Bohr's radius of an atom is: (1) r= n 2 h 2 / 4 Π 2 me 4 z 2 (2) r= n 2 h 2 / 4 Π me 2 z 2 (3) r= n2h2/4 Π me 3
copper reacts with oxygen to form two oxide X and Y .On analysis 1.535g of X yielded 1.365g of copper and 1.450g of Y yielded 1.160g of copper. [I] determine the chemical formula
chemical equation of K2CO3+CH#CH@OH+I2
sources of errors in thermogravimetry
do u do prac Report?
Q. What is Geometrical isomers? Let us take one final example of Ma 2 b 2 cd where the following five isomers are possible as shown in Fig. 'When writing the geometrica
addition of different regent in sample of salt changes its colour
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the equation of langmuir isotherm was derived on basis of
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