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Q. Example on Crystal field splitting in octahedral complexes?
Here four ligands lie in one plane and the other two in a plane perpendicular to the first plane. Six ligands are at the comers of a regular octahedron and they all lie along the three perpendicular axes, s, y and:. Thus we see that all those orbitals which lie in the direction of these axes will experience a stronger force of repulsion as compared to the orbitals which lie between the axes.
The dx2 - y2 and dZ2 orbitals which fie along the axes will be repelled more by the ligands and will be higher in energy than dxy, dyz and dX set of orbitals.
When an electron revolves in a stationary orbit then: (1) It absorbs energy (2) It emits radiation (3) Its energy remains constant (4 )It gains kinetic energy Ans:
Q. Use values of Δ f H and Δ f G to evaluate the standard molar reaction enthalpy and the thermodynamic equilibrium constant at 298.15 K for the oxidation of nitrogen to form a
Ether formation - Hydrocarbon Phenol reacts along with alkyl halides in alkali solution to make phenyl ethers (Williamson's synthesis). The phenoxide atom is a nucleophile and
Al is used as reducing agent for the extraction of metals such as Chromium,Monganes.Explain why? Solution) Al3+ + 3 e- Al Good reducing agents like aluminum have relatively
The energy of electron in hydrogen atom in its grounds state is -13.6 eV. The energy of the level corresponding to the quantum number equal to 5 is: (1) -0.54 eV (2)
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