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Q. Example on Crystal field splitting in octahedral complexes?
Here four ligands lie in one plane and the other two in a plane perpendicular to the first plane. Six ligands are at the comers of a regular octahedron and they all lie along the three perpendicular axes, s, y and:. Thus we see that all those orbitals which lie in the direction of these axes will experience a stronger force of repulsion as compared to the orbitals which lie between the axes.
The dx2 - y2 and dZ2 orbitals which fie along the axes will be repelled more by the ligands and will be higher in energy than dxy, dyz and dX set of orbitals.
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