Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Eqivalent weight of an element, what is n-factor and what is the formula fo...

what is n-factor and what is the formula for calculating it

Liquefaction of gases, Assainment of liquefaction of gases in degr...

Assainment of liquefaction of gases in degree 2 nd sem

Antimicrobials - chemistry in action, Antimicrobials: These are the ch...

Antimicrobials: These are the chemical substances employed to cure infections because of micro-organisms. These are as well known as microbes. Any creature that causes disease

Tests of benzaldehyde - aldehydes and ketones, Tests of benzaldehyde - alde...

Tests of benzaldehyde - aldehydes and ketones (a) It forms a white precipitate with   solution. (b)  It creates a yellow precipitate with 2: 4 dinitrophenyl hydrazines. (

Proteins, why is the isoelectric point of all amino acids not at ph 7 and w...

why is the isoelectric point of all amino acids not at ph 7 and what has the ionisable side chains got to do with it?

Partition coefficient, what is the effect on the distribution of solute if ...

what is the effect on the distribution of solute if the solvents have mutual miscibility

Determine the concentration of hydroxide ion in this buffer, In lab, buffer...

In lab, buffers solution based onto a 0.1 M solution of sodium phosphate at pH7.0.  Within this system, there are three of pK A s like:  12.7, 7.21 and 2.12. Determine the conce

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd