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Q. Describe Linkage Isomerism?
Some ligands can coordinate to the metal through different donor ato...s present in the ligand. They are called ambidentate ligands and they can produce linkage isomer with a metal ion. Isomerism of this kind is shown by the isomeric pair: [(NH3) CoNo2]2+ yellow brown known as nitro compound and : [(NH3) CoNo2]2+red coloured isomer known as nitito complex. Other example is: Compounds with ligands like SCN which can bind through S or N donor atom, or sulphoxides, R2S0, which may combine through S or 0.
I have the following reactions (1)NaOH+CO2+M=NaHCO3+M, K1 (2)NaHCO3+H=Na+H2CO3, K2 (3)2NaHCO3+M=(NaHCO3)2+M, K3 ki''s are the rate constants. Suppose NaHCO3 is a dominating constit
Biodegradable polymers These are the polymers that are degraded through micro-organisms in an appropriate period so that biodegradable polymers and their degraded products do n
Why can butyllithium (BuLi) not be used for deprotonation? The direct alkylation of enolates is often not very efficient for a preparative synthesis due to problems with furthe
Q. Normal functioning of blood? The sixth position marked by X is either occupied by H 2 0 or 0 2 molecules. Impotant thing to note is that Fe 2+ in hemoglobin does not get o
locallized and delocalized bond
Why 2-methyl propanal gives canizzaro Rex.
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Structural needs for hyperconjugation (i) Compound could comprise at least one Sp 2 -hybrid carbon of as well alkene alkyl carbocation or alkyl free radical. (ii) ∝- carbon
Basics of Potentiometry: In this unit, you have learnt about electrode potentials, principles of potentiometer and measurement of potential, different types of reference elect
what is resonence effect on acidity
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