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Q. Describe Linkage Isomerism?
Some ligands can coordinate to the metal through different donor ato...s present in the ligand. They are called ambidentate ligands and they can produce linkage isomer with a metal ion. Isomerism of this kind is shown by the isomeric pair: [(NH3) CoNo2]2+ yellow brown known as nitro compound and : [(NH3) CoNo2]2+red coloured isomer known as nitito complex. Other example is: Compounds with ligands like SCN which can bind through S or N donor atom, or sulphoxides, R2S0, which may combine through S or 0.
Q. Illustrate about square planar complexes? For square planar complexes Mu, Ma3b or Mab3 where a and b etc., are monodentate ligands, again the geometrical isomerism is not p
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An element X with the electronic configuration 1s 2 , 2s 2 , 2p 6 , 3s 2 , would be expected to form the chloride with the formula: (1) XCl 3 (2) Xcl 2 (3) XCl
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