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Q. Describe Linkage Isomerism?
Some ligands can coordinate to the metal through different donor ato...s present in the ligand. They are called ambidentate ligands and they can produce linkage isomer with a metal ion. Isomerism of this kind is shown by the isomeric pair: [(NH3) CoNo2]2+ yellow brown known as nitro compound and : [(NH3) CoNo2]2+red coloured isomer known as nitito complex. Other example is: Compounds with ligands like SCN which can bind through S or N donor atom, or sulphoxides, R2S0, which may combine through S or 0.
Copper crystallizes into a FCC structure and the unit cell has length of edge 3.61 x10-8 cm. Calculate the density of copper if the molar mass of Cu is 63.5 g
Q. Name of the complex anion? The name of the complex anion always ends in 'ate' and the Latin name of the metal atom is used. No specific ending is used for neutral or cationi
1. Acetylation of key proteins is known to correlate with the gene expression in eukaryotes. What class of chromatin proteins is modified? What is the chemical nature of the acetyl
Why can butyllithium (BuLi) not be used for deprotonation? The direct alkylation of enolates is often not very efficient for a preparative synthesis due to problems with furthe
The lactone, a cyclic ester, can form an enolate ion, and this ion is alkylated by methyl iodide.
Antimicrobials: These are the chemical substances employed to cure infections because of micro-organisms. These are as well known as microbes. Any creature that causes disease
Calculate the molar concentration of the solution essential to obtain the value of 10 molecules per µm2. (For this calculation we suppose that the transfer of the dye molecules fro
Manufacture of cement Cement is a composite mixture of calcium silicates & calcium aluminates which is a popular material used for construction. 1) Raw materials : Raw material
show how you would sythesise the following compounds, starting with benzene or toluene and any necessary acyclic reagents. Assume para is the major product.
Applications of radiometric titration in pharmaceutical industry #
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