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Q. Define the Spectrochemical series?
Spectrochemical series helps us in renationalising the differences in the spectral properties of complexes. As the strength of the crystal field created by the ligands & increases, the frequency of absorption of light by the complex would also increase. Absorption of high frequency radiations means that light of lower frequency will be transmitted and will be responsible for the particular dour of the complex. It thus explains as to why the colours of a series of complexes of one particular metal ion, in the same oxidation state having the - same geometry, could be different. For example, the following four octahedral compounds of Co3 ion show different colours which are in accordance with spectrochemical series.
Complex D0 (em-1) colours
[Co (C2O4)3]3- 18,000 Dark green
[Co (H2O)6]3+ 18.200 Blue
[Co (NH3)6]3 + 22.900 Golden-brown
[Co (CN)6]3 - 33.500 Yellow
The electronic configuration of calcium ion ( Ca2 + ) is: (1) 1s 1 , 2s 2, 2p 6 , 3s 2 , 3p 6 , 4s 2 (2) 1s 1 , 2s 2 , sp 6 , 3s 2 , 3p 6 , 4s 1
what is wurtz reaction?
Stability of gem diols lies on the following factors: (a) Steric hindrance by +I group around α-carbon decreases the stability of gem diols. +I group decreases stability of gem
1) A 100 mL 0.4M acetic acid soln is titrated with 0.5M NaOH. Write a reaction equation to work the following: a) What volume of the base would be required to reach the equivalenc
what is arrhenius''s theory
ionic equation by ionelectron method (half reaction)
Distillation under reduced pressure - Purification of organic compounds This process is employed for the purification of high boiling liquids and liquids that decompose at o
Q. Name of the complex anion? The name of the complex anion always ends in 'ate' and the Latin name of the metal atom is used. No specific ending is used for neutral or cationi
(a) De?ne surveying. Brie?y describe about chain and accessories. (b) Sketch the plan and suitable section of a single room having 5.0 m X 4m size and 3m height. Assume the ba
how we determine the compound is ir active or not . and how we determine the polarity of a compound?
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