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Q. Define the Spectrochemical series?
Spectrochemical series helps us in renationalising the differences in the spectral properties of complexes. As the strength of the crystal field created by the ligands & increases, the frequency of absorption of light by the complex would also increase. Absorption of high frequency radiations means that light of lower frequency will be transmitted and will be responsible for the particular dour of the complex. It thus explains as to why the colours of a series of complexes of one particular metal ion, in the same oxidation state having the - same geometry, could be different. For example, the following four octahedral compounds of Co3 ion show different colours which are in accordance with spectrochemical series.
Complex D0 (em-1) colours
[Co (C2O4)3]3- 18,000 Dark green
[Co (H2O)6]3+ 18.200 Blue
[Co (NH3)6]3 + 22.900 Golden-brown
[Co (CN)6]3 - 33.500 Yellow
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Time taken for an electron to complete one revolution in the Bohr orbit of hydrogen atom is: (1) 4 Π mr 2 / nh (2) nh/ 4Π 2 mr (3) nh/ 4Π 2 mr 2
Give chemical reaction in support of each of the following statements: (i) The +1 oxidation state gets stabilised progressively from Ga to TI in Group (ii) All the bonds PCl5
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Q. What do you mean by Rounding off numbers? Rounding off numbers while you report a calculation your answer should have no more significant figures than the piece of data yo
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Give the example of inductomeric effect.
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5Mol K+
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