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Q. Define the Spectrochemical series?
Spectrochemical series helps us in renationalising the differences in the spectral properties of complexes. As the strength of the crystal field created by the ligands & increases, the frequency of absorption of light by the complex would also increase. Absorption of high frequency radiations means that light of lower frequency will be transmitted and will be responsible for the particular dour of the complex. It thus explains as to why the colours of a series of complexes of one particular metal ion, in the same oxidation state having the - same geometry, could be different. For example, the following four octahedral compounds of Co3 ion show different colours which are in accordance with spectrochemical series.
Complex D0 (em-1) colours
[Co (C2O4)3]3- 18,000 Dark green
[Co (H2O)6]3+ 18.200 Blue
[Co (NH3)6]3 + 22.900 Golden-brown
[Co (CN)6]3 - 33.500 Yellow
A covalent bond is likely to be formed between two elements which: (1) Have similar electronegativities (2) Have low ionization energies (3) Have low melting points (4
Hofmann Method - Determination of Molecular Mass The method is applied to those substances that are not stable at their boiling points, but that may be volatilised with no deco
Which of the following sets is possible for quantum numbers : (1) n=4, l=3, m= -2 , s=0 (2) n=4, l=4, m= +2 , s=1/2 (3) n=4, l=3, m= -2 , s=+1/2 (4)
2. A mixture is prepared by adding 25.0 mL of 0.185 M Na3PO4 to 34.0 mL of 0.140 M Ca(NO3)2. (a) What mass of Ca3(PO4)2 will be formed? (b) What will be the concentrations of eac
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