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Q. Define the Spectrochemical series?
Spectrochemical series helps us in renationalising the differences in the spectral properties of complexes. As the strength of the crystal field created by the ligands & increases, the frequency of absorption of light by the complex would also increase. Absorption of high frequency radiations means that light of lower frequency will be transmitted and will be responsible for the particular dour of the complex. It thus explains as to why the colours of a series of complexes of one particular metal ion, in the same oxidation state having the - same geometry, could be different. For example, the following four octahedral compounds of Co3 ion show different colours which are in accordance with spectrochemical series.
Complex D0 (em-1) colours
[Co (C2O4)3]3- 18,000 Dark green
[Co (H2O)6]3+ 18.200 Blue
[Co (NH3)6]3 + 22.900 Golden-brown
[Co (CN)6]3 - 33.500 Yellow
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This is an example of pinacone pinacone rearrangemnt acetone with Mg and H2O forms 2,3 Dimethylbutane2.3 diol which on reacting with H+ from forms first a carbocation on carbon 2
what is this
Silver salt method for acids - Chemical methods It is based upon the fact that silver salt of an organic acid on heating provides residue of metallic silver.
The coordination number of Ni in the complex is 4, the configuration of Ni +2 , at first sight, shows that the complex is formed by sp 3 hybridization and it is paramagnetic an
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Q. What are the Chemical Properties of Halogens? Ans. he halogens have 7 valence electrons in their outermost shell. Note that 7 is one electron short of the octet.
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