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Q. Define the Spectrochemical series?
Spectrochemical series helps us in renationalising the differences in the spectral properties of complexes. As the strength of the crystal field created by the ligands & increases, the frequency of absorption of light by the complex would also increase. Absorption of high frequency radiations means that light of lower frequency will be transmitted and will be responsible for the particular dour of the complex. It thus explains as to why the colours of a series of complexes of one particular metal ion, in the same oxidation state having the - same geometry, could be different. For example, the following four octahedral compounds of Co3 ion show different colours which are in accordance with spectrochemical series.
Complex D0 (em-1) colours
[Co (C2O4)3]3- 18,000 Dark green
[Co (H2O)6]3+ 18.200 Blue
[Co (NH3)6]3 + 22.900 Golden-brown
[Co (CN)6]3 - 33.500 Yellow
Nuclei contain uncharged neutrons and positively charged protons; these two particles with about the same mass are known as nucleons. The number of protons is the atomic number of
Ammonia is oxidised with air to form nitric oxide in the first step to produce nitric acid. The reaction occurs in a well insulated continuous reactor based on the stoichiometry:
The structure of spiropentadiene The structure of spiropentadiene is shown below; it undergoes a Diels-Alder reaction with two molar equivalents of 1,3-cyclopentadiene. Spirope
The interatomic distances in H 2 and Cl 2 molecules are 74 and 198 pm respectively. The bond length of HCl is : (1) 272 pm (2) 1
Depression in freezing point - Physical methods for Non-volatile substances Mol. Mass = (1000 K f * w) /W* ΔT Where, K f stands for Molal depression constant of the solve
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what is the mechanism of acyl chloride reaction with alcohol and why does it react in this way ?
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