Coordination compounds- hybridisation, Chemistry

Assignment Help:

In coordination compounds , how to decide whether itss hybridisation will be sp3d2 or d2sp3.. itss based on inner or outer orbital complex but how will we got to know that for every compound ..plzz explain..?

Ans) In sp3d2 all s,p and d orbitals are from the same energy level. But in d2sp3, d orbital is from (n-1)th energy level.


Related Discussions:- Coordination compounds- hybridisation

Disperse dyes - classification of dyes, Disperse dyes: These dyes are u...

Disperse dyes: These dyes are utilized to colour synthetic fabrics for example orlon, polyesters, nylon and cellulose acetate that comprise tightly bounded structures. The dyes

The abstraction of a hydrogen atom, The abstraction of a hydrogen atom ...

The abstraction of a hydrogen atom The H-CN bond is stronger than the O-H bond, the abstraction of a hydrogen atom from HCN by the tert-butoxy radical is endothermic by 528 - 4

Packing of atoms, how can i make an assignment on this topic

how can i make an assignment on this topic

Dihydric alcohols, prepration,reactions ,uses and reactivity of dihydric a...

prepration,reactions ,uses and reactivity of dihydric alcohols

The electronic configuration of element with atomic number, The electronic ...

The electronic configuration of element with atomic number 24 is : (1) 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 4s 2       (2) 1s 2 2s 2 2p 6 3s 2 3p 6 3d 10         (3)

3/11/2013 3:34:00 AM

The hybridisation of coordination compounds is based on valence bond theory.. if the metal in the coordinate sphere is linked to strong ligands (for e.g. CN-) then the electrons of (n-1)d orbital pair up against hund''''s rule and the vacant spaces therefore formed is used up to combine with the ligands.. this is d3sp3 coz the inner d orbital participates..On the other hand if the ligand is weak (for e.g. F-) then the electrons of (n-1)d orbital of the metal does not pair up..this is sp3d2 coz outer d orbital will participate in bond formation with the ligands...

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd