Coordination compounds- hybridisation, Chemistry

Assignment Help:

In coordination compounds , how to decide whether itss hybridisation will be sp3d2 or d2sp3.. itss based on inner or outer orbital complex but how will we got to know that for every compound ..plzz explain..?

Ans) In sp3d2 all s,p and d orbitals are from the same energy level. But in d2sp3, d orbital is from (n-1)th energy level.


Related Discussions:- Coordination compounds- hybridisation

Dehydration of alcohols, write the structures of the major product (saytzef...

write the structures of the major product (saytzeff elimination) when the following alcohols are dehydrated with hot,concentrated sulphuric acid. 1. 3-methyl-2-butanol 2. 2-pentano

Assignment, LITHIUM AND BERYLLIUM MARKEDLY DIFFERENT FROM OTHER MEMBERS OF ...

LITHIUM AND BERYLLIUM MARKEDLY DIFFERENT FROM OTHER MEMBERS OF THEIR RESPECTIVE GROUP?.

What is the iupac name of carbon?, IUPAC name is given to compounds. Carbon...

IUPAC name is given to compounds. Carbon is an element so it will bw called as carbon only. eg. hydrocarbons - CH4=methane                            C2H6=Ethane

Cid, what is acid

what is acid

F block, Write the electron configuration for Tl why do we use F block and ...

Write the electron configuration for Tl why do we use F block and how do i count the subshells in that case?

The set of quantum numbers & belongs to the element, The set of quantum num...

The set of quantum numbers n= 3, l=0, m=0, s= -1/2 belongs to the element: (1) Mg                   (2) Na        (3) Ne                (4) F Ans: Mg

Armomatic compounds, write the chemical properties of aromatic compounds.

write the chemical properties of aromatic compounds.

The following for which one mathematical expression, Among the following fo...

Among the following for which one mathematical expression γ= h/p  stands: (1) De Broglie equation (2) Einstein equation (3) Uncertainty equation (4) Bohr equation A

The possible values of azimuthal quantum number, When the principal quantum...

When the principal quantum number(n= 3)  , the possible values of azimuthal quantum number(l ) is: (1) 0,  1,  2, 3           (2) 0,  1, 2    (3) -  2, - 1,  0, 1, 2

3/11/2013 3:34:00 AM

The hybridisation of coordination compounds is based on valence bond theory.. if the metal in the coordinate sphere is linked to strong ligands (for e.g. CN-) then the electrons of (n-1)d orbital pair up against hund''''s rule and the vacant spaces therefore formed is used up to combine with the ligands.. this is d3sp3 coz the inner d orbital participates..On the other hand if the ligand is weak (for e.g. F-) then the electrons of (n-1)d orbital of the metal does not pair up..this is sp3d2 coz outer d orbital will participate in bond formation with the ligands...

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd