Chemical thermodynamic properties, Chemistry

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The following cell is used for measuring the partial pressure of oxygen at 700^oC.

(Pt) Cu₂Cu₂0 / 0.85 ZrO₂ - 0.l5 CaO / O₂ (Pt)

Knowing that conduction through the solid electrolyte (calcia stabilized zirconia) is attributed to the O-2 ions, derive the equation relating the cell e.m.f. to the partial pressure of oxygen. Use data from the Chemical Thermodynamic Properties.

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