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Beckmann rearrangement
Ketoxime while treated with acid at 0°C it goes through rearrangement termed as Beckmann rearrangement.
So, acid catalysed conversion of ketoximes to N-substituted amides is known as Beckmann rearrangement. Acid catalyst utilized is proton acids (H2SO4, HCl, H3PO4) and Lewis acids (PCl5, SOCl2, PhSO2Cl, RCOCl, SO3, BF3 etc)
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Acetylene tetrachloride (Westron), CHCl 2 ·CHCl 2 It is as well called as sym. tetrachloroethane. It is made by the action of chlorine on acetylene in existence of a catalyst
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