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Chemical Properties of Aromatic Nitro Compounds - Electrophilic substitution
Because - NO2 group is deactivating and m-directing, electrophilic substitution (halogenation, nitration and sulphonation) in simple aromatic nitro compounds (for example nitrobenzene) is extremely difficult as compared to that in benzene. Therefore vigorous reaction conditions are utilized for such reaction and the new group enters the m-position.
This is an example of pinacone pinacone rearrangemnt acetone with Mg and H2O forms 2,3 Dimethylbutane2.3 diol which on reacting with H+ from forms first a carbocation on carbon 2
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