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Chemical Properties of Aromatic Nitro Compounds - Electrophilic substitution
Because - NO2 group is deactivating and m-directing, electrophilic substitution (halogenation, nitration and sulphonation) in simple aromatic nitro compounds (for example nitrobenzene) is extremely difficult as compared to that in benzene. Therefore vigorous reaction conditions are utilized for such reaction and the new group enters the m-position.
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What is happen whenever H2SO4+HNO3 adding to the phenol.give the reaction Ans) Phenol + HNO3(in prescence of sulphuric acid) --> 2-nitrophenol + 4-nitrophenol.
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