Measure diffusion coefficients is the diaphragm cell

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One easy way to measure diffusion coefficients is the diaphragm cell shown in Fig. 2.2-4. These cells consist of two well-stirred volumes separated by a thin porous barrier or diaphragm. In the more accurate experiments, the diaphragm is often a sintered glass frit; in many successful experiments, it is just a piece of filter paper (see Section 5.5). To measure a diffusion coefficient with this cell, we fill the lower compartment with a solution of known concentration and the upper compartment with solvent. After a known time, we sample both upper and lower compartments and measure their concentrations. Find an equation that uses the known time and the measured concentrations to calculate the diffusion coefficient.

Reference no: EM13704100

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