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Quinone undergoes a reversible reduction at a voltammetric working electrode. The reaction is
(a) Assume that the diffusion coefficient for quinone and hydroquinone are approximately the same and calculate the approximate half-wave potential (versus SCE) for the reduction of hydroquinone at an ROE from a solution buffered to a pH of 7.0.
(b) Repeat the calculation in (a) for a solution buffered to a pH of 5.0.
a laboratory furnace wall is constructed of 0.20m thick fireclay brick having k11.2 wm-degc. this is covered on the
Calculate the operational availability for a power generator with 1 scheduled maintenance per 1000 hours of operation and failure rate of 0.6 failures per 1000 hours.
The maximum flow past a circular cylinder is 2 X the Up stream velocity. The max velocity occurs at the center line of the top of the cylinder.
If the beam has square cross section of 9 in., on each side, determine the absolute maximum bending stress in the beam.
Calculate the expected number of vacancies that will exist in a cubic inch of Aluminum at room temperature (25°C), provided that the activation energy for vacancy formation in Aluminum is equal to 0.75 eV/atom.
the edges of a thin plate are held at the temperature described below. determine the steady-state temperature
using the mechanical energy balance estimate the time required for the water level to drop from an upper piece of tape
if a case of light bulbs contains 1200 bulbs and the probability that any one bulb is defective is 0.015 estimate the
Calculate the force on a wall subjected to a two-phase jet that has the following parameters:
consider a reheat cycle with steam leaving the boiler and entering the turbine at 4 mpa and 400 c . after expanded in
A vertical plate 2.5 m high, maintained at a uniform temperature of 54°C, is exposed to saturated steam at atmospheric pressure.
it has been shown that the cop for a carnot refrigerator. is greater than the cop for a real refrigerator . show the
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