Rate of a reaction, Chemical Kinetics Assignment Help

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Rate of a reaction

The rate (speed or velocity) of a reaction is the change in concentration in per unit time. 

 1907_rate of reaction.png

 

where Δx or dx is the concentration change, which means x2-x1 in the time interval  Δt or dt, which means t2-t1

Concentration is generally expressed in active mass, which is mole L-1

         · The rate measured over long time interval is called as average rate and the rate measured for the infinitesimally small time interval is known as instantaneous rate and

Instantaneous rate  625_rate of reaction1.png

         · For the reaction which is 952_rate of reaction2.png

 

         The rate at which the reactant disappearance is negative in nature

         617_rate of reaction3.png  The rate at which the A disappears

2464_rate of reaction4.png  The rate at which B disappears

Rate of formation of the product is positive in nature

727_rate of reaction5.png  The rate of formation of C

1372_rate of reaction7.pngThe rate of formation of D

         ·  Stoichiometric coefficient rate can be expressed as

                        1575_rate of reaction8.png

         · The reaction's rate is always positive in nature.

         · The reduction is seen in the rate of chemical reaction as the reaction progresses.

         · Unit of rate of a reaction = Unit of conc. / Unit of time=mole L-1 time -1

         In the term of gaseous reaction unit can be defined as atm time-1 and

         Rate in atm time-1= Rate in mole L-1time-1 * RT

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