Mechanism of the reaction, Chemical Kinetics Assignment Help

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Mechanism of the reaction

(1) Reaction making use of first order consecutive reactions

(i) In this kind of reactions, the reactions from the stable intermediate compound before they are finally converted into products.

(ii) For instance, reactants (R) are first converted to intermediate (I) which is then converted to product (P) as

787_Mechanism of reaction.png

 Thus, the reaction takes place in two steps, both of which are of the first order that is

Step I :  781_Mechanism of reaction1.png

This means that I is obtained by step I and consumed by step II. In the above given reactions, each stage will have its own rate and rate constant reactant concentration will always decrease and product concentration will always increase as which is shown in figure

78_Mechanism of reaction2.png

(2) Reaction involving slow step : When a  reaction occurs by a sequence of steps and one of the step is quite slow, then rate determining step is slow step. For instance in the reaction

1097_Mechanism of reaction3.png; , if k1<<k2 then I is converted into the products as soon as it is formed, we get the conclusion as follows

1551_Mechanism of reaction4.png

(3) Parallel reactions : In these type of reactions the reactants are more reactive, which can have different orders of the reactions taking place simultaneously. For example, in a system containing NO2 and SO2, NO2 is consumed in the following two reactions,

894_Mechanism of reaction5.png

         The rate at which the NO2 disappears will be sum of the rates of the two reactions i.e.,

1074_Mechanism of reaction6.png 

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