First law of Thermodynamics and work Assignment Help

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First law of thermodynamics is based on the principle of the conservation of power. According to the first law,

ΔQ = W + ΔU              Where,   ΔQ =  heat given to the system

                        ΔU = Change in internal energy of working fluid (confined ideal gas)        

                          W = Work done by the system         

In applying this law special care must be taken in using the sign convention correctly.

Work

If we take a cylindrical vessel of cross-sectional area A which is filled with ideal gas enclosed by means of a mass less frictionless movable piston, then for an infinitesimal displacement 'dx' of the piston, the pressure of the confined gas can be taken as constant.

So,       Force  = Pressure * Area  = P * A

and      dW  = F dx

            dew = PA dx

            dW = PdV

Total work done by gas for change in volume from V1 to  V 2 ,  W  = 682_First law of Thermodynamics and work1.png

1364_First law of Thermodynamics and work.png

If the volume increases (V2 > V1) the system expands against the external pressure and so the system is doing work (according to sign convention positive work is being done by the system) and vice versa.

 

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