Acetophenone, C₆H₅COCH₃, Acetyl Benzene

         Method of preparation

         (i) Friedel-Craft's reaction : Acetyl chloride reacts with benzene in presence of anhydrous aluminium chloride to form acetophenone.

         (ii) By distillation of a combination of calcium benzoate and calcium acetate.

         (iii) By methylation of benzaldehyde reacted with diazomethane.

         (iv) By reacting benzoyl chloride with dimethyl cadmium.

         (v) By Grignard reagent

              (a) 

               (b) 

         (vi) Commercial preparation : Ethylbenzene is oxidised with air at 126^o C under pressure in presence of a catalyst manganese acetate.

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