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1. Sodium dodecyl sulfate is a detergent with a charged hydrophilic sulfate head group and a 12 carbon hydrocarbon tail. In solid form it exists as a monomeric molecule but upon dissolving in water at room temperature (298 K) it assembles spontaneously (ΔG = -16.4 kJ/mol) into a higher ordered micelle with the structure shown below.
A. Measurements of this process at room temperature show an enthalpy of micelle formation (ΔH) of -1.42 kJ/mol. Calculate the entropy for this reaction. Is micelle formation accompanied by an increase or decrease in the disorder of the system? Explain your answer.
B. Micelle formation is a good example of what type of noncovalent interaction?
C. Micelle formation in the presence of 0.5 M NaCl results in a more negative ΔH value of -8.49 kJ/mol with no further change in entropy compared to micelle formation in water. Is micelle formation more energetically favored in water or 0.5 M NaCl? What noncovalent interaction could account for this change in enthalpy?
Why nuclear fission preceeds nuclear fusion?
INFORMATION ABOUT PRALLEL FORCE
Using Gauss divergence theorem show that the volume of a sphere of radius 'r' is 4⁄3 πr 3 .
Q Calculate the longest wavelength that can be analysed by a rock salt crystal of spacing d = 2.82 Ao in the first order. Data: d = 2.82 Å = 2.82 × 10-10 m; n = 1 ; λmax = ?
On the basis of mutual interactions or behavior of several materials in an external magnetic field, the materials are dividing in three basic categories. (i) Diamagnetic materi
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an object moves from postion +16m to the postion +47m in 12s.what is its total displacement and its average velocity?
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