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Quinone undergoes a reversible reduction at a voltammetric working electrode. The reaction is
(a) Assume that the diffusion coefficient for quinone and hydroquinone are approximately the same and calculate the approximate half-wave potential (versus SCE) for the reduction of hydroquinone at an ROE from a solution buffered to a pH of 7.0.
(b) Repeat the calculation in (a) for a solution buffered to a pH of 5.0.
a u-tube manometer is initially filled with water but exposed to a pressure difference such that the water level on the
Considering only the moments M1 and M2, calculate the maximum tensile stress σt, the maximum compressive stress σc, and the maximum in-plane shear stress τmax at point p, which is located at support A on the side of the bracket at midheight.
A cylindrical pressure vessel of 120 in diameter outside, used for processing rubber, is 36 ft. long. If the cylinder portion of the vessel operates at 120 psi internal pressure, what are the stresses acting on an element at the inside surface of the..
a particle moves along the curve yx2 - 4m with a constant speed of 5 ms. determine the point on the curve where the
one-dimensional steady-state conduction with uniform internal energy generation occurs in a plane wall with a thickness
a hollow steel shaft g 77.2 gpa allowable stress 50 mpa outer diameter 60 mm inner diameter 25 mm length 5 m
providing domestic hot water to a household typically requires 107 kj of energy per year. a typical electric water
a water line is planned to connect a new reservoir to an existing water treatment plant. the average water surface
A model of an airplane is to be tested at 20°C in a wind tunnel. The model is built to 1/12th scale. In order to match both the Mach number and the Reynolds number of the plane, the wind tunnel is pressurized. To what pressure (in atm) should the air..
Air undergoes an isentropic process from P_1 = 100 kPA and T_1 = 300 K to a final state where the temperature is 700 K. Assuming an ideal gas, find P_2 using both the ideal gas tables and assuming a constant specific heat ratio at the average tempera..
r-134a is throttled from 1200kpa and 40 degree c to 200kpa. it is known that heat of 5kjkg is lost from r-134a to the
a gas that is contained in a cylinder undergoes two processes that are in series. the first process from 1 to 2 consist
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