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Consider the proposed mechanism for a reaction below. What is the rate law for the overall reaction?
(1) X + Y â†" Z (fast, reversible)
(2) Z + A â†' B (slow)
(3) B â†' C (fast)
(1) Rate = k[X][Y][A] (2) Rate = k[Z][A][B] (3) Rate = k[X][Y][Z] (4) Rate = k[X][Y] (5) Rate = k[Z][B]
A 0.692 g sample of glucose, C6H12O6, is burned in a constant volume, bomb calorimeter. The temperature change is measured at 1.80 degrees C.
A solution is prepared by adding some solid CaF2 to water and allowing the solid to come to equilibrium with the solution. The equilibrium constant for the reaction below is Kc = 3.9x10-11.
One can safely assume that the 3s- and 3p-orbitals will form molecular orbitals similar to those formed when 2s- and 2p-orbitals interact. According to molecular orbital theory,
A stock solution is prepared by adding 24 mL of 0.4 M Na3PO4 to enough water to make 76 mL. What is the PO43- concentration of 25 mL of the stock solution
2-Methylpentane and 4-methyl-2-pentanone are constitutional isomers with the molecular formula C6H12O.each shows a molecular ion peak in its mass spectrum at m/z 100.
At 212 mm Hg and 24 °C, a sample of gas occupies a volume of 125 mL. The volume is increased to 325 mL and the temperature is reduced to -5.0 °C. What is the final pressure of the gas in the flask?
How many grams of methane CH4 must be combusted to heat 1.15 kg of water from 24.0 C to 93.0 C, assuming H2O as a product and 100% efficiency in heat transfer?
A green leaf has a surface area of 2.00 cm^2. If solar radiation is 1030 W/m^2, how many photons strike the leaf every second? Assume three significant figures and an average wavelength of 504 nm for solar radiation.
An elemental analysis of X shows that the mass percentage composition of the compound is 26.86% C and 2.239% H, with the remainder being oxygen. A mass spectrum of X yields a molar mass of 90.0 g/mol. Write the empirical formula of X.
How much CH4, in grams, is needed to produce 50.0 grams of CHCl3?
What is the percent yield of a reaction in which 282 g phosphorus trichloride reacts with excess water to form aqueous phosphorus acid (H3PO3) and 114 g HCl?
If 2 new elements have been discovered and one is R, a new element from the family with 3 valence electrons and Z, a new element from the family with 6 valence electrons. Write the formula for the binary compound between element R and element Z.
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