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Synthesis of aromatics1. On the basis of electronic theory, explain the following observations:
a. The -N(CH3)2 group is an ortho, para director, and strongly activates the ring, whereas the -N(CH3)3 group is a meta director and deactivates the ring toward electrophilic substitution.b. The -NO2 group is a meta director, and its presence on the ring makes electrophilic substitution more difficult as compared with the -NH2 group, which is an ortho, para director.
2. Devise a suitable reaction sequence in which each of the following compounds can be prepared from benzene in good yield. Assume ortho and para isomers are separate from one another, and use any other reagents you desire.a. p-Bromoisopropylbenzeneb. m-Nitrobenzenesulfonic acidc. p-Tert-butylbenzenesulfonic acidd. m-Xylene
What is the volume occupied by 0.265mol of helium gas at a pressure of 1.28atm and a temperature of 307K
Compute the pH if NaOH solution of the 10.00 mL has been mixed. pKa of HCOOH = 3.74
what is qvib at a temperature of 3100 K, keeping the zero point energy and referenced to v= 0? What is the vibrational contribution to CV, at the temperature 2600 K?
The pH in a lake the size of 4.0 km X 7.0 km and an average depth of 100 m is found to be 4.5. Calculate the mass of calcium carbonate that must be added to the lake water in order to raise its pH to 6.0.
What volume of 0.140 M Hydrochloric acid is required to neutralize 2.68g of Magnesium hydroxide.
The decay constant for strontium-90 = 0.0247y-1. if 10.0 g decay for exactly 60 years then determine how many grams of strontium-90 remain.
A 1.6 g sample of a molecular compound is dissolved in 104 g of tetrachloromethane (carbon tetrachloride). The normal boiling point of the solution is 61.51degreesC, the normal boiling point of CCl4 is 61.2degreesC. The boiling point constant for ..
Metallic magnesium reacts with steam to produce magnesium hydroxide and hydrogen gas. If 17.1 g of Mg are heated with 9 g of H2O, what is the limiting reactant.
Consider the reaction 4KO2(s) + 2CO2(g)->2K2CO3(s) + 3O2(g) . How much KO2 is needed to react with 75.0 L of carbon dioxide at STP?
The volume of the gas is measured 201 mL at .989 atm. compute the number of grams of Na used in the reaction if Vapor pressure of water = 0.0277 atm
How many moles of CO(NH2)2 are present in 105 g of water, if the freezing point of the solution is -4.02C? kf(water) = 1.86 K · kg/mol.
At room temperature (about 20degree C) milk turms sour in about 64 hours. In a refrigerator at 3 degree C, milk can be stored for about three times as long before turning sour.
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