The oxidation of benzyl alcohol to benzaldehyde, Chemistry

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In which region can these properties of the fluid be tuned more simply - near the critical point or at higher pressure/temperature (consider the critical constants and the results of 5.2)?

The oxidation of alcohols by molecular oxygen in supercritical carbon dioxide, e.g. the oxidation of benzyl alcohol to benzaldehyde, is a supercritical process. The reaction takes place in the presence of a Pd/Al2O3 catalyst with a selectivity of 95%. 

 


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