Chemical thermodynamic properties, Chemistry

The following cell is used for measuring the partial pressure of oxygen at 700oC.

(Pt) Cu2Cu20 / 0.85 ZrO2 - 0.l5 CaO / O2 (Pt)

Knowing that conduction through the solid electrolyte (calcia stabilized zirconia) is attributed to the O-2 ions, derive the equation relating the cell e.m.f. to the partial pressure of oxygen. Use data from the Chemical Thermodynamic Properties.

 

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