Chemical process analysis, Chemistry

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A useful model of interfacial mass transport makes three assumptions:

(i) there is a difference between the concentrations of A at the interface, CA denoted CA in Phases I and II, respectively, and the bulk concentrations.

(ii) the rates of transfer in each phase are proportional to the differences between the bulk an interfacial concentrations:

1424_Chemical Process Analysis.png

(iii) the interfacial concentrations are in equilibrium:

1152_Chemical Process Analysis2.png

(A) Show that the equation

594_Chemical Process Analysis1.png

(B) Find the limit of Km in the following cases:

1885_Chemical Process Analysis3.png

(C) What is the physical significance of the two limits in part (B)?


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