chemical combination, Chemistry

laws of chemical combination
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Which one of the following set of quantum numbers is not possible for 4p  electron : (1) n=4, l=1, m=-1, s= +1/2                 (2) n=4, l=1, m=0, s= +1/2          (3) n=

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Which of the metal ion will have highest number of unpaired electrons: (1) Cu +                  (2)  Fe +       (3) Fe 3+                             (4) Co 2+ A