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For the binary system 2, 4-dimethylpentane (1) + benzene (2) the excess Gibbs energy of the liquid phase is given by:
GE/(x1x2) = (A12x1 + A21x2)
a. Calculate the constants A12 and A21 if γ*1 = 1.958 and γ*2 = 1.478
b. Calculate at 60°C the pressure and composition of the vapor phase which is in equilibrium with a liquid phase with composition x1 = 0.5. At this temperature the saturated vapor pressures of component 1 and 2 are respectively 52.4 and 52.3 kPa. The vapor phase is ideal and the Poynting correction can be ignored.
c. Calculate Henry's constant of component 2 in pure component 1 and of component 1 in pure component 2.
What is the phase rule and what does it indicate? Gibbs' phase rule is the fundamental rule on which phase diagrams are based. It gives the number of degrees of freedom for a g
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