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The enthalpy of combustion, ?Hºcombustion, of oxalic acid, H2C2O4(s), is -246.05 kJ mol-1. Consider the following data: Substance ?Hºf (kJ mol-1) Sº (J mol-1 K-1) C (s) 0 5.69 CO2 (g) -393.5 213.6 H2 (g) 0 130.6 H2O (l) -285.8 69.96 O2 (g) 0 205.0 H2C2O4 (s) ? 120.1 (1) 2H2C2O4 + O2 -> 2H2O + 4CO2 (2) H2 + 2C + 2O2 -> H2C2)4 a) Use the information in the table above and the equations (1) and (2) to calculate ?Hºf for oxalic acid. b) Calculate ?Sºf for oxalic acid and ?Sº for the combustion of one mole of oxalic acid. c) Calculate ?Gºf for oxalic acid and ?Gº for the combustion of one mole of oxalic acid.
Calculate the concentrations of all species in a 1.01 M Na2SO3 (sodium sulfite) solution
What is the mole fraction of acetone, C3H6O, in the vapor phase from a solution consisting of a mixture of acetone and ethyl acetate, CH3COOCH2CH3, at 30.00 °C, if the total pressure above the solution is 184.6 torr?
Consider the titration of 30mL of 0.030 M of NH3 with 0.030M HCl. Calculate the pH after the following volumes of titrant have been added
The manometer shown below measures the pressure of the water in the tank. Using variables for the densities (no values given), find the gage pressure at point A.
Calculate the zero-point energy of a harmonic oscillator consisting of a rigid CO molecule adsorbed to a metal surface by a bond of force
If 0.130 mol a third gas is added with no change in volume or temperature, what will the total pressure become?
The standard molar enthalpy of vaporization for water is 40.79 kJ/mol. What mass of steam is required to release 500. kJ of energy upon condensation? (Molar mass of water is 18.02 g/mol.)
The glass electrode used in commercial pH meters gives an electrical response proportional to the concentration of hydrogen ion. To convert these responses to a pH reading
reversible expansion from Pinitial=25.0 bar and Vinitial=4.50L to Pfinal=4.50 bar, (2) a single step irreversible expansion against a constant external pressure of 4.50 bar
Iranian President Mahmoud Ahmadinejad has a mass of 130 lbs. If Iran abandoned it's nuclear energy program and instead converted its President entirely to energy
Diethyl ether is a volatile organic compound. The vapor pressure of diethyl ether is 401 mm Hg at 18°C and the Hvap = 26.0 kJ/mol. Calculate the vapor pressure of diethyl ether at 40°C.
The iron (55.847 g/mol) in a 700.0 mL sample of a natural water was determined by precipitation of the cation as hydrated Fe2O3. The precipitate was filtered
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