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In deoxyhemoglobin, Iron atom lies ~0.36 to 0.40 out of the plane of the heme group whereas in oxyhemoglobin it lies of the porphyrine plane. Give reason for this behavious. Talk in terms of coordination number, size and the oxidation state of the iron.
Draw the correct structure for (3S,4S)-3,4-dimethylhexane. Show stereochemistry clearly. To ensure proper grading, explicitly draw all four groups, including wedge/dash bonds
For the following acid-base equilibrium, label the stronger acid, stronger base, weaker acid, and weaker base. Predict whether the position of equilibrium lies toward the right
Solution 1.0C 1xF 1.8F 32F2 to carry out the desired conversion. When the absolute temperature is 400 K, what is the Fahrenheit temperature?
Calculate the pH of a solution of 15 mL K2HPO4 at 0.1 molarity,
A gaseous system undergoes a change in temperature and volume. What is the entropy change for a particle in this system if the final number of microstates is 0.407 times
how far will they be separated (in cm) from each other on a plate when the solvent front is developed to 15cm? Draw an approximate picture if what the TLC slide would look like.
Calculate the de Broglie wavelength of an neutron moving at 1% the speed of light. Calculate the velocity of a neutron with a wavelength of 75pm.
The procedure (paragraphs 2 and 3) states that the additions of bromobenzene, methyl benzoate and hydrochloric acid must be done slowly.
Trehalose is the major sugar in the hemolymph (blood) of many insects. Insects have open circulatory systems that bathe the tissues of the animal.
Calculate the amount of these reactants required to produce 14 grams of 5-methyl-5-nonanol assuming an 80% yield.
Consider a distillation column that is fed 1000 kg/hr of an equimolar mixture of benzene and cyclohexane. Theof the benzene distillate stream is to contain 90 % with a benzene mole fraction of 0.95.
Gold has a face-centered cubic arrangement with a unit cell edge length of 4.08 Angstrom. How many moles of gold fit in a sheet with a length of 51.6 nm, a width of 24.3 nm, and a thickness of 16.7 nm?
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